A new method for preparing SWNT/epoxy nanocomposites has been developed which involves high shear mixing of the epoxy resin and SWNT and heat treating the mixture prior to introducing the hardener. The glass transition temperature of the epoxy resin is unaffected by the presence of nanotubes. An improvement of 17% in flexural modulus and 10% in flexural strength has been achieved at 0.05 wt% of...

The polymer possessing with planar structure can be activated and guided to encapsulate the inner space of SWNT and form a helix through van der Waals interaction and the π-π stacking effect between the polymer and the inner surface of SWNT. The SWNT size, the nanostructure and flexibility of polymer chain are all determine the final structures. The basic interaction between the polymer and the...

A generic noncovalent approach for dispersing high concentrations of individual single-walled carbon nanotubes (SWNT) in organic as well as aqueous solutions of synthetic block copolymers is presented. It is suggested that a weak, long-ranged entropic repulsion among polymer-decorated tubes acts as a barrier that prevents the tubes from approaching the attractive part of the intertube potential...

By using molecular dynamics simulation, we have investigated systematically the feasibility of continuous unidirectional water flux across a deformed single-walled carbon nanotube (SWNT) driven by an oscillating charge outside without osmotic pressure or hydrostatic drop. Simulation results indicate that the flux is dependent sensitively on the oscillating frequency of the charge, the distance ...

The thermal properties of single-walled carbon nanotubes (SWNTs) are of significant interest, yet their dependence on SWNT chirality has been, until now, not explored experimentally. Here, we used electrical heating and infrared thermal imaging to simultaneously study thermal and electrical transport in chirality-sorted SWNT networks. We examined solution processed 90% semiconducting, 90% metal...

Using classical molecular dynamics simulations, we have studied thermal boundary conductance (TBC) between a single-walled carbon nanotube (SWNT) and surrounding Lennard-Jones (LJ) fluids. With an aim to identify a general model that explains the TBC for various surrounding materials, TBC was calculated for three different surrounding LJ fluids, hydrogen, nitrogen, and argon in supercritical ph...

Titanium dioxide/single-walled carbon nanotube (TiO2/SWNT) composites were prepared for photocatalytic applications. The composites were characterized using UV-visible and Raman spectroscopy, zeta-potential measurements, cyclic voltammetry (CV) coupled with a photoreactor, scanning electron microscopy (SEM) and transmission electron microscopy (TEM) coupled with energy dispersive x-ray spectros...

Single-walled carbon nanotubes (SWNTs) can be dispersed as individuals in H2O using sodium dodecylsulfate (SDS), typically at 1% (35 mM) concentration. At and above the critical micellar concentration (cmc 8 mM at 25 °C), the degree of ionization of SDS is 0.27.1 Once intertube van der Waals (VdW) attraction is overcome by intense sonication, free SDS adsorbs to SWNT surfaces and creates a net ...

A two-terminal semiconducting single-walled carbon nanotube (SC-SWNT) film in contact with an ionic liquid allows the realization of an extremely high density of holes, inducing a strong position-dependent electromodulation of the interband and excitonic transitions as a result of the position-dependent shift of the SWNT Fermi level. Electrical control of the optical transmission suggests appli...

The chemical reactivity of carbon nanotubes in H2SO4 is investigated using individual, single-walled carbon nanotubes (SWNTs) incorporated into electronic devices. Exploiting the device conductance as a sensitive indicator of chemical reactions, discrete oxidation and reduction events can be clearly observed. During oxidation, a SWNT opens circuits to a nanometer-scale tunnel junction with resi...