نتایج جستجو برای: tetrazine

تعداد نتایج: 409  

Journal: :Journal of the American Chemical Society 2010
Juliane Schoch Manfred Wiessler Andres Jäschke

There is currently a tremendous interest in developing bioorthogonal "click chemistry" methods for the modification of biopolymers. Very recently, inverse-electron-demand Diels-Alder reactions have received attention, but to date they have not been applied to nucleic acids. Here we describe the first example of DNA modification by inverse-electron-demand Diels-Alder reaction. We synthesized fou...

2015
Mohammad Rashidian Edmund J. Keliher Michael Dougan Patrick K. Juras Marco Cavallari Gregory R. Wojtkiewicz Johanne T. Jacobsen Jerre G. Edens Jeroen M. J. Tas Gabriel Victora Ralph Weissleder Hidde Ploegh

We generated F-labeled antibody fragments for positron emission tomography (PET) imaging using a sortase-mediated reaction to install a trans-cyclooctenefunctionalized short peptide onto proteins of interest, followed by reaction with a tetrazine-labeled-F-2-deoxyfluoroglucose (FDG). The method is rapid, robust, and site-specific (radiochemical yields > 25%, not decay corrected). The availabili...

Journal: :Acta Crystallographica Section E Structure Reports Online 2010

Journal: :Acta Crystallographica Section E Structure Reports Online 2012

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