Until now, the potential effects of titanium dioxide (TiO2) nanoparticles on endothelial cells are not well understood, despite their already wide usage. Therefore, the present work characterizes six TiO2 nanoparticle samples in the size range of 19 × 17 to 87 × 13 nm, which are commonly present in sun protection agents with respect to their physicochemical properties (size, shape, ζ-potential,...

here we present our experimental results in synthesizing au-cu nano-particles with tunable localized surface plasmon resonance frequency through wet-chemical at temperature room. the reaction is performed in the presence of ascorbic acid as a reducing agent and polyvinyl pyrrolidone as capping agent via four different procedures: (1) mixture of 90% haucl4 and 10% cuso4.5h2o precursors, (2) mixt...

We fabricated a sandwich-like branched-polyethyleneimine (b-PEI)/TiO2/Au/graphene oxide (GO) nanocomposite through a biomimetic layer-by-layer co-mineralization approach, and the polymer b-PEI was believed to act as both an inducing agent for the hydrolysis of titanium bis(ammonium lactato)-dihydroxide (Ti-BALDH) and a reducing agent for the reduction of HAuCl4 in the synthetic procedure. Upon ...

Absorption spectra (150-300 nm) of TiO2 and TiO2 modified with metal (Pt, Pd, and Au) nanoparticles were systematically measured using an attenuated total reflection-far ultraviolet spectrometer. The deposition of metal nanoparticles altered the spectral shape and intensity, indicating changes in the electronic states and photocatalytic activities of TiO2.

This study uses molecular dynamics simulations performed in a parallel computing environment to investigate the adsorption of water molecules surrounding Au nanoparticles of various sizes. An observation of the oxygen and hydrogen atom distributions reveals that the adsorption of the water molecules creates two shell-like formations of water in close vicinity to the Au nanoparticle surface. The...

The embedding of oxide nanoparticles in polymer matrices produces a greatly enhanced dielectric response by combining the high dielectric strength and low loss of suitable host polymers with the high electric polarizability of nanoparticles. The fabrication of oxide–polymer nanocomposites with well-controlled distributions of nanoparticles is, however, challenging due to the thermodynamic and k...

A partially reduced TiO2 surface exhibits increasingly complex nature when forming various defects, whose stoichiometry, structure and properties are markedly different from those of bulk TiO2. Using scanning tunneling microscopy and density functional theory, we investigate different types of surface defects formed by Ti interstitials on TiO2 (110) and their reactivity toward deposited gold at...

The current work reports on the development of Au nanoparticles (NPs) supported titania membrane towards enhancing catalytic reduction p-nitrophenol. Titania was successfully fabricated via chemical anodization method at 50 V in ethylene glycol: water as electrolyte. A well-ordered nanotubular array 138±18 nm pore diameter observed by electron microscope. NPs were deposited form (Au/TiO2 MF) im...

Under UV-visible light irradiation, multiple synergetic promotion effects on the photocatalytic activity of TiO2 by gold deposition can be observed, and plasmonic Au/TiO2 shows great potential for photocatalytic solar conversion.