The asymmetric unit of the title mol-ecular salt, C(19)H(15)N(4) (+)·I(-), contains four 2,3,5-triphenyl-2H-tetra-zol-3-ium cations and five iodide anions, with two of the latter lying on crystallographic inversion centres. In each cation, the tetra-zole ring is essentially planar (r.m.s. deviations = 0.004-0.007 Å). The dihedral angles between the tetra-zole ring and its three attached benzene...

The six-membered thio-pyran ring in the title compound, C(26)H(24)S, adopts a boat conformation, with the S atom displaced by 0.478 (2) Å and the 3-methyl-ene C atom by 0.644 (2) Å from the plane of the other four sp(2)-hydridized C atoms. The methyl group on the methyl-ene carbon lies in a pseudo-equatorial position and the phenyl ring in a pseudo-axial position.

Tris complexes of Ln3+ ions (Ln = La, Ce, Pr) with triphenyl-substituted cyclopentadienyl ligands were studied by optical spectroscopy. Emission both 5d - 4f and transitions was observed for Pr3+ complex. It found that the strength crystal field formed in tris is comparable to case sulfides, as a result, red luminescence Ce3+ compound. The quantum yield photoluminescence 20% latter.

phosphorus (p) is one of the most vital elements for all living organisms which acts as aconstituent of essential biomolecules such as nucleic acids, phospholipids, and phosphosugars,and as a major contributor to almost all metabolic reactions including photosynthesis,respiration, and energy delivery. it is one of the most needed nutrients for plant growth anddevelopment. despite high levels of...

Ab s t r a c t . The effect of organic-metallic compounds including lead, (C6H5)3PbCl, and tin, (C6H5)3SnCl, on cucumber leaves and green algae Scenedesmus quadricauda were studied. Both compounds, in concentration of 2 μmol dm, caused increased emission of ultra weak chemiluminescence (UCL) of cucumber leaf discs after 20 hours of treatment, and activity of tin triphenyl chloride was stronger ...

Through a diffusion reaction, cuprous bromide, triphenyl-phosphane and 1,3-bis-(pyridin-4-yl)propane (bpp) were self-assembled to form the one-dimensional title compound, [Cu(2)Br(2)(C(13)H(14)N(2))(C(18)H(15)P)(2)](n). Each Cu(I) atom is coordinated by two Br atoms, one P atom from a triphenyl-phosphane ligand and one N atom from a bpp mol-ecule in a distorted tetra-hedral geometry. Two μ(2)-B...

Growing numbers of synthetic chemicals have potential endocrine-disrupting effects and cause ecological health risks. However, the primary toxicity pathways mechanisms endocrine disruption are poorly understood existing risk assessment relies heavily on animal testing. Database mining, omics technology, computer simulation can serve as an alternative approach to explore by building adverse outc...

Reaction of ethyl (Z)-3-(heteroaryl/aryl)-2-((triphenyl-λ5-phosphaneylidene) amino) acrylates intermediates with 2,3-thiophenedicarboxaldehyde was used in novel Tandem three consecutive reactions: aza-Wittig, imine condensation and electrophilic heteroaromatic cyclization to obtain a series indolizines. A tentative mechanism this reaction is proposed.