Several low oxidation state aluminum-containing cluster anions, LAlH- and LAln- (n = 2-4, L = N[Si(Me)3]2), were produced via reactions between aluminum hydride cluster anions, AlxHy-, and hexamethyldisilazane (HMDS). These clusters were characterized by mass spectrometry, anion photoelectron spectroscopy, and density functional theory (DFT) based calculations. Agreement between the experimenta...

Automobiles are required to be even lighter for further achieving environmental protection through fuel economy improvement, as well as safety feature enhancement and drivability improvement. Automotive suspensions are also required to reduce their weight and thus more aluminum is being adopted. Aluminum forgings, in particular, are often applied because of their significant weight reduction ef...

Aluminum, a non-redox-active metal is, nevertheless, a pro-oxidant both in in vitro preparations and in vivo. It facilitates both superoxide- and iron-driven biological oxidation by mechanisms that remain to be resolved. More than 10 years ago Fridovich and colleagues suggested that the facilitation of superoxide-driven biological oxidation by aluminum was due to an interaction between the meta...

Corrosion and subsequent waterwall wastage has been a significant problem for coal-burning power companies since low NOx burner conditions have been implemented in their furnaces. In order to reduce the amount of waterwall corrosion, coatings for the boiler tubes, such as weld overlay claddings, are currently being pursued. Iron-aluminum based coatings are presently being studied as possible co...

Aluminum lamination was performed to improve the physical and mechanical properties of several wood-based composite panels. The panels were aluminum-laminated on two faces in a hot press at 689 kPa and 120 °C for 6 min. Four types of wood-based composites were used as cores, and aluminum 3003 alloy sheets were used for face laminations. Polyurethane adhesive ensured bonding strength between the...

Although aluminum is known to be toxic to most organisms, its precise biochemical interactions are not fully understood. In the present study, we demonstrate that aluminum promotes the inhibition of aconitase (Acn) activity via the perturbation of the Fe-S cluster in Pseudomonas fluorescens. Despite the significant decrease in citrate isomerization activity, cellular survival is assured by the ...

Strain UHM-5, a pSym Exo derivative of the aluminum-tolerant Rhizobium leguminosarum bv. phaseoli strain CIAT899, was equally tolerant of aluminum (Al) as the parental culture. Dialyzed culture supernatants of the wild-type cells grown in YEM broth (10 cells ml) contained 185 mug of glucose equivalents ml whereas UHM-5 culture supernatants yielded 2 mug of glucose ml. The Exo derivative and the...

Maize (Zea mays L) is the most important food grain in sub-Saharan Africa and is mostly grown by small-scale farmers under rainfed conditions. Aluminum toxicity caused by low pH is one of the abiotic factors limiting maize production among smallholder farmers. Therefore, breeding maize hybrids that are tolerant to aluminum toxicity will sustain and increase maize production in these areas. Henc...

Aluminum is the most abundant metal and the third most abundant element in nature. Combined with oxygen and silicon it occurs as feldspar. KASJ308, mica, KISi04, and Kaolin, H2AI2SJ208H20. Although aluminum salts have been used for various purposes since ancient times the free metal was not isolated until 1827 when Wohler reduced aluminum chloride with potassium. Commercial utilization of free ...

Aluminum has no defined biological function and it is potentially involved in the pathogenesis of neurodegenerative disorders. Furthermore, the presence of fluoride causes more aluminum to accumulate in the brain, resulting in increased neuronal damage. In recent years, resveratrol through its ameliorative effects was found to be a neuroprotectant. This study reports the protective effects of r...