The applications of carbon nanotubes (CNTs) as catalysts have attracted much interests in catalysis community due to their unique porous microstructure and chemical properties. One of the promising results is the use of CNTs in the oxidative dehydrogenation (ODH) of ethylbenzene to styrene [1,2]. However, only few works were reported on the use of CNTs or other carbonaceous materials to catalyz...

Heterotrophic cell suspension cultures of Ruta graveolens were established by reversion of photom ixotrophic cultures without any change in the chemical composition of the growth medium. The heterotrophic cultures were qualitatively and quantitatively analyzed by gaschromatography and mass spectroscopy for volatile compounds. The terpenoid hydrocarbons geijerene and pregeijerene, C6-C8 ketones,...

We present new spectroscopic observations of the 3.4μm absorption feature in the Seyfert galaxies, NGC1068 and NGC7674, and the ultraluminous infrared galaxy, IRAS08572+3915. A signature of C H bonds in aliphatic hydrocarbons, the 3.4μm feature indicates the presence of organic material in Galactic and extragalactic dust. Here we compare the 3.4μm feature in all the galaxies in which it has bee...

the aim of this research is to develop a silica gel and alumina column chromatography for separation of polycyclic aromatic hydrocarbons (pahs) and polychlorinated biphenyls (pcbs) into two groups. this is achieved by optimizing the cut-off volume of eluting solvent and weight ratio of silica gel and alumina. in this process mixture of pahs and pcbs divide in two groups and simultaneously other...

AIM The parent of xGraptoveria, Graptopetalum paraguayense, is used in Chinese folk medicine for alleviating hepatic disorders, detumescence and detoxication, lowering of blood pressure, inhibition of cancer cells, exerting diuretic effects, relieving pain and infections. No data are available regarding its anti-conjunctivitis effect. The aim of this preliminary study is to test the anti-conjun...

Halogenated aliphatic compounds were evaluated for toxic and genotoxic effects in the somatic mutation and recombination test employing Drosophila melanogaster. The tested chemicals included chlorinated, brominated and iodinated; mono-, di- and tri-substituted; saturated and unsaturated alkanes: 1,2-dibromoethane, 1-bromo-2-chloroethane, 1-iodopropane, 2,3-dichloropropene, 3-bromo-1-propene, ep...

Methods for selective oxidation of aliphatic C-H bonds are called on to revolutionize organic synthesis by providing novel and more efficient paths. Realization of this goal requires the discovery of mechanisms that can alter in a predictable manner the innate reactivity of these bonds. Ideally, these mechanisms need to make oxidation of aliphatic C-H bonds, which are recognized as relatively i...

Introduction: Polycyclic aromatic hydrocarbons (PAHs) are small organic matters found also in the interstellar space [1]. They are subjects of interest as distant ancestors of organic matters in our Solar system, in view of the life cycle of solid matters in space. Data and analysis: AKARI, Japanese infrared astronomical satellite, surveyed all the sky in the 9, 18, 65, 90 and 160 micron bands....

This study aimed to establish primary reactions and identify gaseous products during fast pyrolysis of low-density polyethylene (LDPE), polypropylene (PP) polystyrene (PS). Fast was performed by using Py-GC/MS/FID at 574 ± 22 °C for 5 s. Gaseous fractions formed LDPE, PP PS were 14 1 wt%, 31 3 wt% 103 12 respectively. The main compounds from LDPE butane, 1-pentane 1-hexene. gave propene, pentan...

Custom-designed surfactants, known as "linactants", have the ability to reduce the line tension between coexisting phases within mixed monolayers of chemically dissimilar compounds at the air-water interface. Thus far, linactants have been successfully identified for only one type of chemical dissimilarity, involving mixed monolayers of hydrocarbon and fluorocarbon surfactants. In the present w...