On the basis of stable alkaline earth metal ammines, a series of M(NH3)6NaCl and M(NH3)6Na2 (M = Mg and Ca) excess electron compounds were theoretically constructed and studied by using the density functional theory. The electride or alkalide characteristics of these compounds are verified by their electronic structures, HOMOs, and small VIE values. It is worth noting that the M(NH3)6Na2 alkali...

The extraction method is critical for the recovery of phenolic compounds. The main goal was to evaluate the effect of an extraction process from mango seed on their phenolic profile, antioxidant and antimicrobial capacities. Phenolic extraction was performed in different steps: maceration, alkaline hydrolysis, acid/alkaline hydrolysis, polar and non-polar fraction of an ethyl acetate separation...

This paper provides an overview of hydrometallurgical copper extraction studies in which liquid technology has been used with four deposits different compositions. The sulfuric acid consumption rate and efficiency, are dependent on the initial content forms calcium compounds other impurities ore samples, were calculated, results presented herein. It was established that during leaching process,...

We report on the formation of mixed alkali-alkaline earth molecules (LiCa) on helium nanodroplets and present a comprehensive experimental and theoretical study of the ground and excited states of LiCa. Resonance enhanced multiphoton ionization time-of-flight (REMPI-TOF) spectroscopy and laser induced fluorescence (LIF) spectroscopy were used for the experimental investigation of LiCa from 1500...

The use of autoionization as a tool to quantitatively analyze transitions between high-n strontium Rydberg states with low-to-intermediate values L is described and demonstrated through observations Rabi oscillations when driving 5snf 1F3 → 5s(n + 1)g 1G4, 2)h 1H5, 5snp 1P1 1)d 1D2 using microwave fields. technique shown offer advantages compared selective field ionization can be used other alk...

The electronic and structural possibilities of a recently conceived, as-yet unsynthesized, AM6E8 (or A2M6E8) structural type are explored. With A an alkaline earth metal, M a transition metal, and E a main group element, a range of geometries containing M–M pairs with very short separations is feasible. Density functional theory geometry optimizations and an extended Hückel analysis of the bond...

Abstract Multifunctional materials that are capable of facilitating multiple electrocatalytic processes highly desirable. This work reports the observation bifunctional properties for water‐splitting in layered oxides, featuring 2‐dimensional layers octahedrally coordinated transition metals separated by alkaline‐earth or rare‐earth metals. Remarkably, these able to catalyze both half‐reactions...

The surface properties of fatty acid and fatty acid-alcohol mixtures were examined at 22-24 degrees C. At pH 12, sodium stearate forms a rigid surface film that generates an equilibrium spreading pressure of 16.5 dynes/cm. At pH 12, stearate-alkaline earth cation films collapse at the air-water interface and do not generate significant equilibrium spreading pressures. The rate of film collapse ...