Monodisperse crystalline zero-valent iron, iron-nickel, iron-palladium nanowires were synthesised using template-directed electrodeposition methods. Prior to nanowire fabrication, alumina nanotemplates with controlled pore structure (e.g. pore diameter and porosity) were fabricated by anodising high purity aluminium foil in sulphuric acid. After fabrication of alumina nanotemplates, iron, iron-...

Ultra-high purity alumina was sintered in hydrogen at temperatures ranging from 13251 to 20201C. Normal grain growth was maintained in all samples and grain boundary mobilities were measured. The data represent the most complete measure of intrinsic grain boundary mobility for alumina grain growth currently available. There are two orders of magnitude of discrepancy between the calculated and m...

Al2O3:SiOC nanocomposites were synthesized by thermal treatment of fumed alumina nanoparticles modified by phenyltrimethoxysilane. The effect of annealing temperature in inert ambient on structure and photoluminescence of modified alumina powder was studied by IR spectroscopy as well as photoluminescence spectroscopy with ultraviolet and X-ray excitation. It is demonstrated that increase of ann...

9 = 0.6 I / s ' 7 = 6.0 0 7 = 2 4 i ti 3 = 6 0 Through close control over green-state powder processing, pure alumina ceramics of 0.5-pm grain size were obtained by sintering at 1250°C. The static grain growth of this material was modest at temperatures below 1300°C. However, dynamic grain growth occurred rapidly during superplastic deformation. Therefore, although the ultrafine-grained alumina...

Here, we present a systematic study about the effect of the pore length and its diameter on the specular reflection in nanoporous anodic alumina. As we demonstrate, the specular reflection can be controlled at will by structural tuning (i.e., by designing the pore geometry). This makes it possible to produce a wide range of Fabry-Pérot interferometers based on nanoporous anodic alumina, which a...

The quality of the refractories applied on integrated gasification combined cycle should be a key factor that affects both the reliability and the economics of gasifier operation. To enhance the workability of chromia/alumina castables, three types of ultrafine alumina powder were added to improve the workability. Densification behavior of such castables in the presence of ultrafine alumina was...

The rapid development of the global aluminum industry has led to a considerably increasing consumption of bauxite, from which alumina is mostly produced. Many aluminum producing countries including China have to import bauxite to keep the growth of native industry due to the low quality of bauxite. The costs of alumina production as well as the other aluminum-related products are correspondingl...

Despite the widespread use of amorphous aluminosilicates (ASA) in various industrial catalysts, the nature of the interface between silica and alumina and the atomic structure of the catalytically active sites are still subject to debate. Here, by the use of dynamic nuclear polarization surface enhanced NMR spectroscopy (DNP SENS) and density functional theory (DFT) calculations, we show that o...

The reaction of γ-alumina with tetraethylorthosilicate (TEOS) vapor at low temperatures selectively yields monomeric SiO(x) species on the alumina surface. These isolated (-AlO)3Si(OH) sites are characterized by PXRD, XPS, DRIFTS of adsorbed NH3, CO, and pyridine, and (29)Si and (27)Al DNP-enhanced solid-state NMR spectroscopy. The formation of isolated sites suggests that TEOS reacts preferent...