The structure and phase sequence of liquid-mercury-supported Langmuir films (LFs) of anthrone and anthralin were studied by surface tensiometry and surface-specific synchrotron X-ray diffraction. In the low-coverage phase the molecules are both side-lying, rather than the flat-lying orientation found for anthracene and anthraquinone. In the high-coverage phase, the molecules are either standing...

An anthraquinone-linked duplex DNA oligomer containing 60 base pairs was synthesized by PCR. The strand complementary to the quinone-containing strand has four isolated GG steps, which serve as traps for a migrating radical cation. Irradiation of the quinone leads to electron transfer from the DNA to the quinone forming the anthraquinone radical anion and a base radical cation. The radical cati...

A versatile and simple methodology for the creation of mixed monolayers on glassy carbon (GC) surfaces was developed, using an osmium-bipyridyl complex and anthraquinone as model redox probes. The work consisted in the electrochemical grafting on GC of a mixture of mono-protected diamine linkers in varying ratios which, after attachment to the surface, allowed orthogonal deprotection. After opt...

Alkali ratios and cooking time of the alkaline sulfite anthraquinone (AQ) and methanol (ASAM) pulping process of bamboo (Gigantochloa scortechinii) were studied. Bamboo chips were cooked at three different levels of sodium hydroxide and cooking time, namely 14, 16, or 18% for 60, 90, or 120 minutes. Pulping parameters that remained constant were the use of 0.5% ethylene diamine tetraacetic acid...