The interaction of a macrocycle's aggregates with a guest molecule has special interest due to the double role, both of macrocycle cavity and self-associates, in the binding of the guests. Here, we report on the interactions of nonaggregated methyl-substituted (SCA1) and aggregated penthyl-substituted (SCA2) tetramethylenesulfonated calix[4]resorcinarenes with pH indicators methyl yellow (MY) a...

a convenient and efficient direct protocol for the preparation of antibacterial azo dyes by the reaction of 2-naphthol with aromatic amines in the presence of catalytic amount of n-methyl-2-pyrrolidonium hydrogen sulfate ([h-nmp]hso4) was carried out under solvent free conditions. this method has some advantages such as: easy work-up and easy separation of catalyst from the reaction mixture. th...

A convenient, rapid, and one-pot method for the synthesis of azo dyes has been developed. In this protocol, diazotization reagent (ArN2+ -CrO3–SiO2) was prepared via grinding of aromatic amines, NaNO2, wet SiO2 and nano silica chromic acid (Nano-SCA) without solvent at room temperature. The obtained diazotization reagent was suff...

A convenient, rapid, and one-pot method for the synthesis of azo dyes has been developed. In this protocol, diazotization reagent (ArN2+ -CrO3–SiO2) was prepared via grinding of aromatic amines, NaNO2, wet SiO2 and nano silica chromic acid (Nano-SCA) without solvent at room temperature. The obtained diazotization reagent was suff...

Background & Aims of the Study: Azo Dyes are the most hazardous materials in different industries. Dyes and pigments used in industries for applications such as textiles, leathers, papers, foodstuffs, additives, etc. Application amounts of azo dyes in industries which can cause severe health problems in human and environmental pollutant problems. So, color wastewaters decomposition plan are...

Wastewaters from the industrial sector and, in particular, those textile industry have a diverse composition of organic dyes. These dyes are xenobiotics for living organisms falling into natural water, can lead to severe consequences aquatic flora and fauna. This is case with azo-dyes, such as, example, amaranth. The adaptive responses micro- metafauna communities activated sludge towards shock...

In recent years many investigations have been carried out on the carcinogenic activity of several groups of derivatives of 4-aminoazobenzene, their spectra, the relative basicities of their nitrogen atoms, and their metabolism (1, 2, 9, 14). The principal results on the correlation of structure and activity are as follows: Methylation.--3'-Methyl-4-dimethylaminoazobenzene is a tvery potent carc...