The Coulombic interaction in the oriented attachment growth of one-dimensional nanotubes is evaluated via a newly-derived analytical expression of the Coulombic interactions between a spherical attaching nanoparticle and a growing nanotube. The correlation between the interaction and the important growth parameters, including nanoparticle/nanotube size, aspect ratio, and nanoparticle-nanotube s...

A quantum capacitance is calculated for a single wall carbon nan otube in a eld e ect device The calculation is performed on a base of a continuum model taking into account full microscopics A general ex pression for the atomistic capacitance of a nanotube of arbitrary shape is derived The result is useful for modeling of electromechanical action of a nanotube device and for nanotube electronic...

Large-scale CdSe nanotube arrays on indium tin oxide (ITO) glass have been synthesized using ZnO nanorod template. The strong visible light absorption in CdSe, its excellent photoresponse, and the large surface area associated with the tubular morphology lead to good visible light-driven photocatalytic capability of these nanotube arrays. Compared to freestanding nanoparticles, such one-piece n...

We have investigated reversible single-wall carbon nanotube (SWNT) oxidation by quantitative analysis of the oxide-induced absorption bleaching and luminescence quenching at low pH. These data, in combination with DFT structure calculations, suggest that the nanotube oxide is a 1,4-endoperoxide. At low pH, the endoperoxide protonates to create a hydroperoxide carbocation, introducing a hole in ...

We combine ab initio density functional theory with transport calculations to provide a microscopic basis for distinguishing between good and poor metal contacts to nanotubes. Comparing Ti and Pd as examples of different contact metals, we trace back the observed superiority of Pd to the nature of the metal-nanotube hybridization. Based on large scale Landauer transport calculations, we suggest...

We demonstrate reversible wetting and filling of open single-wall carbon nanotubes with mercury by means of electrocapillary pressure originating from the application of a potential across an individual nanotube in contact with a mercury drop. Wetting improves the conductance in both metallic and semiconducting nanotube probes by decreasing contact resistance and forming a mercury nanowire insi...

We have used single-walled carbon nanotube transistors to measure changes in the chemical potential of a solution due to redox-active transition-metal complexes. The interaction of the molecules with a gold electrolyte-gate wire changes the electrostatic potential sensed by the nanotube, which in turn shifts the gate-voltage dependence of the nanotube conductance. As predicted by the Nernst equ...

We have created a tunable mechanical nanoscale resonator with potential applications in precise mass, force, position, and frequency measurement. The device consists of a specially prepared multiwalled carbon nanotube (MWNT) suspended between a metal electrode and a mobile, piezo-controlled contact. By exploiting the unique telescoping ability of MWNTs, we controllably slide an inner nanotube c...

We have measured the electrical resistance R between the ends of a multiwall carbon nanotube during telescopic extension of the nanotube. R increases monotonically with extension and is hysteresis free, demonstrating that a telescoping nanotube constitutes a near-ideal nanometer-scale rheostat. The functional form of R is nonlinear and consistent with an exponential form predicted for a one-dim...