The mixed-valent cerium(III/IV) oxide clusters {Ce(10)} and {Ce(22)}, derived from condensation reactions of cerium carboxylate coordination polymers, exhibit molecular growth tendencies similar to those of 'classical' group V and VI polyoxometalates, but with increasing nuclearity approach the structure of the parental oxide, CeO(2).

Abstract Global warming has received widespread attention in recent years due to the accumulation of carbon dioxide. Looking at current energy landscape, new technologies must be developed reduce CO 2 emissions. The present work is aimed develop and test a prototype an innovative reactor for conversion into CO, operating according two-phase thermochemical cycle. main aspect this study was use c...

Abstract Cerium dioxide CeO 2 (ceria) is an important material in catalysis and energy applications. The intrinsic Frenkel Schottky defects can impact a wide range of properties including the oxygen storage capacity, redox cycle, ionic thermal transport. Here, we study on structural dynamics ceria using density functional theory. phonon contributions to free are found reduce defect formation en...

Undoped and cerium doped LaCO(3)OH annular-shaped nanoarchitectures with high specific surface area have been fabricated via the thermolysis of Ce(x)La(1-x)(oleate)(3) (x = 0-20 mol %) complexes in a toluene-water system containing tert-butylamine/oleylamine. The products exhibit 400 nm-sized monodisperse annular-shaped nanoarchitectures, which are constituted of 3-5 nm-sized primary particles....

Lanthanide ions are promising for the labeling of silica nanoparticles with a specific luminescent fingerprint due to their sharp line emission at characteristic wavelengths. With the increasing use of silica nanoparticles in consumer products, it is important to label silica nanoparticles in order to trace the biodistribution, both in the environment and living organisms.In this work, we synth...

In this research, cerium recycling was studied by Adsorbing Colloid Flotation (ACF). Ten important parameters including collector type and dosage, cerium and colloid concentrations, frother type, activator type, preparation and frothing time, air flowrate and pH, each in two levels, were investigated. Statistical design of experiment was implemented for process modelling and analysis of var...

On the basis of optimized grinding/heating cycles developed for several phosphate-based ceramics, the preparation of brabantite and then monazite/brabantite solid solutions loaded with tetravalent thorium, uranium, and cerium (as a plutonium surrogate) was examined versus the heating temperature. The chemical reactions and transformations occurring when heating the initial mixtures of AnO2/CeO2...

The effect of sulfur on the water-gas-shift (WGS) activity of Pd/ceria catalysts has been studied using steadystate rate measurements, pulse-reactor studies, and FTIR. After exposing Pd/ceria to SO2 at 673 K in an oxidizing environment, the WGS rates dropped to a value close to that observed on Pd/alumina. Both pulsereactor and FTIR measurements showed that cerium sulfates can be readily reduce...

OBJECTIVE To investigate the effect of cerium chloride, cerium chloride/fluoride and fluoride application on calcium release during erosion of treated dentine. METHODS Forty dentine samples were prepared from human premolars and randomly assigned to four groups (1-4). Samples were treated twice a day for 5 days, 30s each, with the following solutions: group 1 placebo, group 2 fluoride (Elmex ...