Two isostructural 1D compounds {[M3(hpdc)2(H2O)6] 2H2O}n (M = Mn, Co; H3hpde = 2-hydroxypyrimidine-4,6-dicarboxylic acid) were synthesized by the in situ hydrothermal reactions of 2-chloropyrimidine-4,6-dicarboxylic acid with MCl2 (M = Mn, Co) and NaOH; the MnII compound shows spin-canted antiferromagnetism, whereas the CoII compound exhibits the coexistence of spin-canting and a two-step field...

Metallic materials in practical use are normally exposed to corrosion in the atmospheric and aqueous environments. Metallic corrosion is one of the problems we have often encountered in our industrialized society; hence it has been studied comprehensively since the industrial revolution in the late eighteenth century. Modern corrosion science was set off in the early twentieth century with the ...

Corrosion tests of 316L and two intermetallic compounds Fe3AI and FeCrSi in industrial Galvanizing (Zn-0.18Al), GALFAN (Zn-5AI), GALVALUME (Zn-55AI), and Aluminizing (AI-8Si) baths and lab-scale static baths were conducted. In on-line tests in industrial hot-dip baths, 316L steel shows better corrosion resistance than Fe3AI in Galvanizing, GALFAN, and GALVALUME baths. The corrosion resistance o...

In this paper, a new kind of carbon steel (CS) and stainless steel (SS) galvanic sensor system was developed for the study of rebar corrosion in different pore solution conditions. Through the special design of the CS and SS electronic coupons, the electronic resistance (ER) method and zero resistance ammeter (ZRA) technique were used simultaneously for the measurement of both the galvanic curr...

To investigate the gradual failure of high-density polyethylene (HDPE) geomembrane as a result of long-term corrosion, four dynamic corrosion tests were conducted at different temperatures and durations. By combining tension and puncture tests, we systematically studied the variation law of tension and puncture properties of the HDPE geomembrane under different corrosion conditions. Results sho...

Eight retrieved metal-on-metal total hip replacements displayed corrosion damage along the cobalt-chromium alloy liner taper junction with the Ti alloy acetabular shell. Scanning electron microscopy indicated the primary mechanism of corrosion to be grain boundary and associated crevice corrosion, which was likely accelerated through mechanical micromotion and galvanic corrosion resulting from ...

In this paper, the corrosion residual strength of the AZ91D magnesium alloy in the presence of sulfate-reducing bacteria is studied. In the experiments, the chemical composition of corrosion film was analyzed by a scanning electron microscope with energy dispersive X-ray spectroscopy. In addition, a series of instruments, such as scanning electronic microscope, pH-meter and an AG-10TA materials...

Corrosion is a significant maintenance problem, especially for aging aircrafts, with the Air Force recently estimating corrosion maintenance costs exceeding $800M per year. Nondestructive evaluation (NDE) techniques can be used to detect corrosion under paint and hidden within layered structures. However, it is difficult to capture a comprehensive picture of the corrosion environment using any ...

Corrosion of reinforcement is one of the main durability problems of concrete structures. The corrosion induces several structural damages which affect the serviceability and the safety of concrete structures. The structural risk is promoting the possibility of embeded sensors which could give alerts in order to repair the structure before reaching dangerous levels of damage. There are an incre...

Corrosion control can be initiated in many ways and may involve either a reduction in corrosion rate or corrosion prevention. Electrolytic corrosion can be prevented by removing a corrosion parameter such as oxygen, moisture or the soluble ions that form the electrolyte. Removing moisture will prevent the formation of an electrolyte solution and is normally cheaper and technically less challeng...