Microporous poly(vinylidene fluoride) (PVDF) membranes were prepared from PVDF/N,N-dimethylacetamide (DMAC) solutions by using upercritical CO2 phase inversion process. As revealed by scanning electron microscope (SEM) and differential scanning calorimeter (DSC), he PVDF membranes exhibit morphological characteristics resulting from both liquid–liquid phase separation and crystallization, i.e.,...

Separation is one of the most important process in all the chemical industries and the gas absorption is the simplest example of separation process which is generally used for the absorption of dilute components from a gaseous mixture. In the present work, a dynamic system of mathematical equation (algebraic and differential) is modeled to predict the behavior of the absorption column using mat...

Supercritical fluid chromatography (SFC) covers a wide range of analyte polarity and application range. For example, SFC offers modifier-free separations of highly hydrophobic compounds using exclusively CO2, which makes SFC a truly green separation technique. Conversely, it is a common phenomenon that isocratic separations may lead to peak broadening of late-eluting compounds due to various ba...

The gas-liquid membrane contactor (GLMC) is a promising alternative gas absorption/desorption configuration for effective carbon dioxide (CO2 ) capture. The physicochemical properties of membranes may synergistically affect GLMC performances, especially during the long-term operations. In this work, commercial polypropylene (PP) and polyvinylidene fluoride (PVDF) hollow fiber (HF) membranes wer...

The field of metal-organic framework based mixed matrix membranes (M(4)s) is critically reviewed, with special emphasis on their application in CO2 capture during energy generation. After introducing the most relevant parameters affecting membrane performance, we define targets in terms of selectivity and productivity based on existing literature on process design for pre- and post-combustion C...

Chemical-Looping Combustion (CLC) is an emerging technology for CO2 capture because separation of this gas from the other flue gas components is inherently to the process and thus no energy is expended for the separation. For its use with coal as fuel in power plants, a process integrated by coal gasification and CLC would have important advantages for CO2 capture. This paper presents the combu...

The effect of carbon dioxide (CO2) sorption on the lower critical solution temperatures of deuterated polybutadiene/polyisoprene blends was determined with in situ small-angle neutron scattering. CO2 was a poor solvent for both polymers and exhibited very weak selectivity between the blend components. The sorption of modest concentrations of CO2, at pressures up to 160 bar, induced phase segreg...

New aspects of substance separation by the laser driven diffusion of gaseous mixtures through capillaries are presented. By using the chopped radiation of a low power CO2 laser, the experimental dependence of the separation coefficient on the pulse frequency in mixtures containing resonant and non-resonant gases was investigated. The induced effects agree with a model in which the number densit...

Covalent organic framework (COF) membranes used for selective removal of CO2 were believed as an efficient and low-cost solution to energy and environmental sustainability. In this study, the amide modified COF nanosheet cluster with a 2D structure was facilely prepared through solid reaction, exhibiting good adsorption-based CO2 selectivity (223 at 273 K and 90 at 298 K) toward N2. Remarkably,...