A critical analysis is presented of the operating temperature windows for nine candidate fusion reactor structural materials: four reduced-activation structural materials (oxide-dispersion-strengthened and ferritic/martensitic steels containing 8–12%Cr, V–4Cr–4Ti, and SiC/SiC composites), copper-base alloys (CuNiBe), tantalum-base alloys (e.g. Ta–8W–2Hf), niobium alloys (Nb–1Zr), and molybdenum...

The permeance of Pd–Cu alloys containing 40, 53, 60, and 80 wt.% Pd has been determined over the 623–1173 K temperature range for H2 partial pressure differences as great as 2.6 MPa. Pure palladium and copper membranes were also evaluated. The Pd–Cu alloys exhibited predictable permeances that reflected the crystalline phase structures as shown in the binary phase diagram. Under conditions of f...

Ag-Cu alloy catalysts for ethylene epoxidation have been shown to yield higher selectivity towards ethylene oxide compared to pure Ag, the unique catalyst employed in the industrial process. Previous studies showed that under oxidizing conditions Cu forms oxide layers on top of Ag. Using first-principles atomistic simulations based on density functional theory, we investigate the reaction mecha...

Nowadays bimetallic nanoparticles (NPs) have emerged as key materials for important modern applications in nanoplasmonics, catalysis, biodiagnostics, and nanomagnetics. Consequently the control of bimetallic structural motifs with specific shapes provides increasing functionality and selectivity for related applications. However, producing bimetallic NPs with well controlled structural motifs s...