The present study explores the temperature and time dependence of heterogeneous (HET) crystal nucleation in a lithium disilicate glass using the stochastic approach. In particular, a single lithium disilicate sample was repeatedly (284 runs) undercooled to 1173K in a PtRh-crucible and the crystallization onset time during an isothermal hold was detected in each run. The statistical distribution...

Experiments show high-speed spinning of many synthetic bers is accompanied by the partial crys-tallization of the initially amorphous melt. This crystallization is induced by some combination of the extensional ow, molecular orientation and extension, and temperature dependence. The crystallization of the material couples back to aaect the ber rheology, through a process of stress-hardening. Re...

Cholesterol crystallization in bile is affected by phosphatidylcholine (PtdCho) hydrophobicity. The aim of the present study was to determine whether PtdCho species modulate the metastable-labile limit and equilibrium solubility of cholesterol in the micellar phase of bile, thereby altering the distribution of cholesterol to biliary lipid carriers and thus influencing cholesterol crystallizatio...

In this paper we present a fast model system for monitoring the recrystallization of quench-cooled amorphous xylitol using Raman spectroscopy and wide-angle X-ray scattering. The use of these two methods enables comparison between surface and bulk crystallization. Non-ordered mesoporous silica micro-particles were added to the system in order to alter the rate of crystallization of the amorphou...

The physicochemical aspects of protein crystallization in reduced-gravity environments ( micro g) have been investigated with the Advanced Protein Crystallization Facility during six space missions. This review summarizes the results, dealing with the mechanisms of nucleation and crystal growth and with the quality of the crystals that were obtained under reduced gravity as well as under normal...

Solute clustering and partitioning behavior in the early crystallization stage of an Fe73.5Si13.5B9Nb3Cu1 amorphous alloy have been studied by employing a three dimensional atom probe (3DAP) and a high resolution electron microscope (HREM). 3DAP results have clearly shown that Cu atom clusters are present in the amorphous state after annealing below the crystallization temperature. The density ...

Most pharmaceutical manufacturing processes include a series of crystallization processes to increase purity with the last crystallization used to produce crystals of desired size, shape, and crystal form. The fact that different crystal forms (known as polymorphs) can have vastly different characteristics has motivated efforts to understand, simulate, and control polymorphic crystallization pr...

The NIST/NASA/CARB Biological Macromolecule Crystallization Database (BMCD), NIST Standard Reference Database 21, contains crystal data and crystallization conditions for biological macromolecules. The database entries include data abstracted from published crystallographic reports. Each entry consists of information describing the biological macromolecule crystallized and crystal data and the ...

Heterogeneous nucleation is often the precursor to crystallization in solution-processed organic semiconductor thin films. Here, we study the efficacy of a series of nine small-molecule organic semiconductor additives in seeding the crystallization of solution-processable triethylsilylethynyl anthradithiophene (TES ADT). By systematically varying the concentrations of the additives in TES ADT t...

Salt crystallization can severely damage anisotropic foliated rocks, therefore it is necessary to have an understanding of crystallization process. The present study was conducted to investigate the effect of salt crystallization on Arakʾs calcareous slates, as anisotropic rocks of Mesozoic. To compare salt crystallization weathering (EN 12370 norm was used up to 30 cycles) with natural weather...