a method for the degradation of pyrrolidine in water is described. the method relaies on the photocatalytic degradation of pyrrolidine to co2 and nh3 by uv irradiation and using titanium dixide semiconductor as a photocatalyst. compared with direct photolysis, the semiconductor catalytic photolysis gave consistently higher degradation yields for pyrrolidine in water. the effects of variable par...

4-(Dimethylamino)pyridine (4-DMAP, 1) is well known as a catalyst for the esterification of alcohols by acid anhydrides and for various other synthetically useful transformations involving acyl transfer. 2] Its catalytic potential was first discovered by the groups of Litvinenko and Steglich in the late 1960s and its synthetic utility and that of its congeners, including polymeric variants, hav...

Chemical modification of chitosan is increasingly studied for its potential of providing new applications of chitosan. Here, a group of novel chitosan quaternary ammonium derivatives containing pyridine or amino-pyridine were designed and successfully synthesized through chemical modification of chitosan. Pyridine and amino-pyridine were used as functional groups to improve the antifungal activ...

the present study has been focused on the acid and base transesterification of animal fats (dairy cow and beef) to produce biodiesel by varying process parameters such as catalyst amount, catalyst nature, reaction time and temperature. the maximum biodiesel yield after acid catalysis was 94.1 ± 2.43 and 98.4 ± 2.3 percent for dairy cow and beef tallow, respectively. the quantity of biodiesel ob...

This work reports, immobilization the Cobaloxime [Co (DH) Cl;DH,dimethylglyoximato)] onto the MCM- .The surface of MCM- was initially functionalized with -aminopropyltrimethoxysilane and -pyridine. For the electrostatic immobilization this was reacted with Cobaloxime and immobilization was achieved by an electrostatic interaction between the Co Cobaloxime and the N of the pyridine and NH amine....

1. Several species of micro-organisms that were capable of utilizing pyridine compounds as carbon and energy source were isolated from soil and sewage. Compounds degraded included pyridine and the three isomeric hydroxypyridines. 2. Suitable modifications of the cultural conditions led to the accumulation of pyridinediols (dihydroxypyridines), which were isolated and characterized. 3. Three spe...

in this research, zeolite a was synthesized from waste porcelain and cds nano-particles were doped in zeolite framework by a precipitation after an ion exchanging process. all raw and modified samples were characterized by ft-ir, xrd and sem methods. primary experiments showed that the good efficiency of loaded nano cds onto the zeolite a for photodecomposition of dimethyldisulfide (dmds) under...

removal of thiosulfate (s2o32-, 200 mg/l) from simulated wastewater samples was investigated under varying co-pollutants and ph conditions employing the titanium dioxide (tio2) mediated photocatalysis. for thiosulfate only studies higher substrate removal was noted at lower ph with a specific trend of ph 4 > ph 7 > ph 10. furthermore, near complete thiosulfate removal was also achieved at ph 4....

Hybrid materials are intensely studied for potential applications in heterogeneous catalysis. Organic groups at the catalyst surface can modify not only its hydrophilicity, but also acidity, hydrothermal stability, porosity, etc. In some cases, tuning such properties leads to improved catalytic performance. Often, however, organic moieties limited methyl introduced via post-grafting. Here, a se...