A new process route for the valorization of BOF steel slags combining H2 production and CO2 mineral sequestration is investigated at 300°C (HT) under hydrothermal conditions. A BOF steel slag stored several weeks outdoor on the production site was used as starting material. To serve as a reference, room temperature (RT) carbonation of the same BOF steel slag has been monitored with in situ Rama...

U-Pb and Hf isotope analyses of zircons from felsic granulite xenoliths in Mesozoic volcanics reveal Early Archean ($3.6 Ga) lower crust beneath the younger (,2.85 Ga) southern margin of the North China craton, and suggest that the eastern part of the craton formed a coherent block by 3.6 Ga. Hf model ages indicate extraction of protoliths from the mantle ca. 4 Ga or earlier, followed by remelt...

In this study, slag penetration into a magnesia refractory monolithic was investigated by the crucible test method. A synthetic calcium aluminate slag system has been used to study commercial magnesia mix refractory for 1, 2, 3, 4, 5 and 6 hours at 1450°C and 1600°C. It has been shown that the penetration rate is controlled by a diffusion mechanism at 1450°C. In this case, capillaries are the ...

Environmental and economic factors increasingly encourage higher utility of industrial by-products. The basic objective of this study was to identify alternative source for good quality aggregates which is depleting very fast due to fast pace of construction activities in India. EAF oxidizing slag as a by-product obtained during the process in steel making industry provides great opportunity to...

Extremely alkaline ground water has been found underneath many shuttered steel mills and slag dumps and has been an impediment to the cleanup and economic redevelopment of these sites because little is known about the geochemistry. A large number of these sites occur in the Lake Calumet region of Chicago, Illinois, where large-scale infilling of the wetlands with steel slag has created an aquif...

The paper embodies the influence of thermal treatment on the morphology, composition and leaching behaviour of titania slag. When Ti-slag was subjected to heat treatment, it developed pores and oxidized at high temperature. This slag consists mainly of a M3O5 phase with an orthorhombic structure. The decrepitation was studied by oxidizing the titania slag sample produced in a pot/muffle furnace...

In the entrained-flow gasifiers used in integrated gasification combined cycle (IGCC) plants, the majority of mineral matter transforms to liquid slag on the wall of the gasifier and flows out the bottom. However, a small fraction of the mineral matter is entrained (as fly ash) with the raw syngas out of the gasifier to downstream processing. This molten/sticky fly ash could cause fouling of th...

Multi-faceted experiments were conducted to measure the properties of several mold slags, needed for fundamental characterization of heat transfer and friction in the interfacial gap between the shell and mold during the continuous casting of steel. A novel apparatus was used to measure the friction coefficient between solidified mold flux and copper at elevated temperatures. The measured softe...

Despite reported synergies between alumina rich supplementary cementitious materials (SCMs) and limestone, previous studies have focused on up to 5% limestone content. Slag hydration in the presence of 10% limestone is reported in this paper. Hydration was followed through chemical shrinkage, calorimetry, thermal analysis, electron microscopy and X-ray powder diffraction. The results show that ...