Mg(2+) is essential for the proper folding and function of RNA, though the effect of Mg(2+) concentration on the free energy, enthalpy, and entropy landscapes of RNA folding is unknown. This work exploits temperature-controlled single-molecule FRET methods to address the thermodynamics of RNA folding pathways by probing the intramolecular docking/undocking kinetics of the ubiquitous GAAA tetral...

Interfacial evaporation from light-absorbing, porous materials have offered an exciting opportunity to utilize sustainable renewable solar energy for desalination. However, the efforts understand fundamental mechanisms governing interfacial greatly lagged behind performance studies. Herein, a hybrid nanofibrous hydrogel-reduced graphene oxide (NHrG) membrane is demonstrated in this work. We exp...

A test substance with characteristics and properties similar to those of cellulose· based solid waste products is needed to calibrate calorimeters and combustors which will be routinely burning these materials to determine their calorific values precisely for use in commerce. Microcrystalline cellulose was found to be a good calibrant for this purpose. The enthalpy of combustion of microcrystal...

The phenomenon of entropy-enthalpy (S-H) compensation is widely invoked as an explanatory principle in thermodynamic analyses of proteins, ligands, and nucleic acids. It has been suggested that this compensation is an intrinsic property of either complex, fluctuating, or aqueous systems. The questions examined here are whether the observed compensation is extra-thermodynamic (i.e., reflects any...