The free radical dispersion polymerization of styrene (St) and methyl methacrylate (MMA) initiated by poly(oxyethylene) (PEO) macroazoinimer (MIM-400) in water/ethanol, was investigated at three different temperatures (50, 60 and 80 8C) for seven polymerization times (3, 6, 9, 12, 24, 36 and 48 h). PStPEO and PMMA-PEO networks were obtained. In each case, polymer gel fractions depend on the pol...

Petroleum-derived monomers are the most common building blocks for ester-based thermosets. Bio-derived thermoset elastomers becoming viable alternatives to conventional Herein, we developed a biobased vitrimer-type using abundant and sustainable raspberry ketone as feedstock. We utilize create dynamic oxime chemistry crosslinked these through free radical polymerization with poly(ethylene glyco...