The mol-ecule of the title Schiff base compound, C(18)H(12)Cl(2)F(6)N(2), adopts an E configuration with respect to the azomethine C=N bond. Intra-molecular C-H⋯F (× 2) and C-H⋯Cl (× 2) hydrogen bonds generate S(5) ring motifs. The imino group is coplanar with the aromatic ring. Within the mol-ecule, the planar units are parallel, but extend in opposite directions from the methyl-ene bridge, as...

The title compound, [Au(C18H10F4PS)Cl2], crystallizes as neutral mol-ecules, with the Au(III) atom coordinated by two Cl atoms and by the P and S atoms of the bidentate phosphanyl thiol-ate ligand, in a slightly distorted square-planar environment. The mol-ecules are linked into centrosymmetric dimers via long axial Au-Cl bonds of 3.393 (4) Å. This axial Au-Cl distance is longer than is usually...

The title complex, [Os(C(6)F(5)S)(3)Cl(C(18)H(12)F(3)P)], displays a trigonal-bipyramidal Os(IV) coordination geometry with the S atoms of three thiol-ate ligands occupying the equatorial positions. The thiol-ate penta-fluoro-phenyl substituents are all placed above the equatorial plane, forming a claw-like cavity which accommodates the chloride ligand with a normal Os-Cl bond length. The phosp...

A series of paddlewheel diruthenium(ii, ii) complexes with various chlorine-substituted benzoate ligands (Cl-series) was synthesized as tetrahydrofuran (THF) adducts [Ru2(ClxPhCO2)4(THF)2]; where ClxPhCO2(-) = o-chlorobenzoate, ; m-chlorobenzoate, ; p-chlorobenzoate, ; 2,3-dichlorobenzoate, ; 2,4-dichlorobenzoate, ; 2,5-dichlorobenzoate, ; 2,6-dichlorobenzoate, ; 3,4-dichlorobenzoate, ; 3,5-dic...

Oscillator strengths for transitions in Cl ii and iii are derived from lifetimes and branching fractions measured with beam-foil techniques. The focus is on the multiplets at 10718 in Cl ii and 10118 in Cl iiiwhose lines are seen in spectra acquired with the Far Ultraviolet Spectroscopic Explorer. These data represent the first complete set of experimental f-values for the lines in the multiple...

In the title compound, (C(8)H(6)F(3)N(2))(2)[HgCl(4)]·2H(2)O, the Hg(II) cation is coordinated by four Cl(-) anions in a distorted tetra-hedral geometry. In the crystal, the 2-trifluoro-methyl-1H-benzimidazolium cations link to the [HgCl(4)](2-) complex anions and lattice water mol-ecules via N-H⋯Cl and N-H⋯O hydrogen bonds, and the lattice water mol-ecules further link to the Hg complex anion ...

In the title compound {systematic name: 1-(2-hy-droxy-eth-yl)-4-[3-(2-trifluoro-methyl-10H-phenothia-zin-10-yl)prop-yl]piperazine-1,4-diium dichloride dimethanol disolvate}, C(22)H(28)F(3)N(3)OS(2+)·2Cl(-)·2CH(3)OH, the dihedral angle between the planes of the two outer benzene rings of the tricyclic phenothia-zine system is 46.91 (13)°. The piperazine ring adopts a chair conformation. The crys...

Density Functional Theory (DFT) calculations were employed to investigate the structural characteristics, electronic properties, and nonlinear optical properties of Benzyne-Based Chromophores at B3LYP/6-31G(d,p) level. The effects on the hyperpolarizabilities of various donor and acceptor substituent (H, F, Cl, Br, Me, NH2, OH, NH3+, COOH, CHO, CN, NO,NO2 ) were studied. The results reveale...

apoptosis, or programmed cell death, is an essential physiological process that plays a critical role in development and tissue homeostasis. caspases, a family of cysteine-dependent aspartate-directed proteases, play a critical role in the initiation and execution of apoptosis. in this study, cytotoxicity and apoptogenic effect of 2-phenyl 4-carboxamide derivatives were evaluated in sknmc (huma...