Mononuclear mono- and bis-chelated iron(iii) complexes [Fe(Phimp)(H2O)(OMe)Cl], 1, [Fe(Phimp)Cl2], 2, [Fe(Me-Phimp)Cl2], 3, [Fe(N-Phimp)Cl2], 4, [Fe(Phimp)2](ClO4), 5, [Fe(Me-Phimp)2](NO3)·H2O, 6·H2O, and [Fe(N-Phimp)2](ClO4), 7, derived from tridentate ligands, have been synthesised and characterized. The X-ray crystal structures of the complexes 2, 4, 5 and 6·H2O were determined. The high-spi...

The title extended solid coordination compound, {[Fe(C(44)H(40)N(2)O(4)P(2))(C(3)H(7)NO)(2)](ClO(4))(2)·2C(3)H(7)NO}(n), was crystallized un-ex-pectedly from the reaction mixture containing the Trost ligand (1R,2R)-(+)-1,2-diamino-cyclo-hexane-N,N'-bis-(2'-di-phenyl-phosphinobenzo-yl) and Fe(ClO(4))(2)·6H(2)O in a 1:1 ratio in dimethyl-formamide (DMF) under reflux conditions. The polymeric comp...

Let Fe be the set of faulty edges of Sn and E0 be the edge set of some pairwise vertex-disjoint paths of Sn. In [5], the authors showed that E0 lies on a Hamiltonian path P (u, v) of Sn−Fe where d(u, v) is odd, |Fe| ≤ n− 3, |E0| ≤ 2n− 7− 2|Fe|. In this paper we improve the previous result as follows: E0 lies on a Hamiltonian path P (u, v) of Sn − Fe where d(u, v) is odd, Fe ≤ n− 3, |E0| ≤ 2n− 6...

N-bridged diiron tetra-tert-butylphthalocyanine activates H(2)O(2) to form anionic hydroperoxo complex [(Pc)Fe(IV)=N-Fe(III)(Pc)-OOH](-) prone to heterolytic cleavage of O-O bond with the release of OH(-) and formation of neutral diiron oxo phthalocyanine cation radical complex, PcFe(IV)=N-Fe(IV)(Pc(+)˙)=O. ESI-MS data showed stability of the Fe-N-Fe binuclear structure upon formation of this s...

The IR spectra of adsorbed CO and NO probe molecules were used to characterize the coordination chemistry of Fe(2+) ions in solution ion exchanged Fe,H/SSZ-13 zeolites. The effects of Fe ion exchange levels, as well as the sample pre-treatment conditions, on the adsorption of these probe molecules were investigated. The ion exchange levels (in the range of the study) did not affect significantl...

Calprotectin (CP) is an abundant metal-chelating protein involved in host defense, and the ability of human CP to bind Fe(ii) in a calcium-dependent manner was recently discovered. In the present study, near-infrared magnetic circular dichroism spectroscopy is employed to investigate the nature of Fe(ii) coordination at the two transition-metal-binding sites of CP that are a His3Asp motif (site...

We report that the (Ba,K)Fe(2)As(2) superconductor (transition temperature, T(c) approximately 38 K) has an inverse iron isotope coefficient alpha(Fe) = -0.18(3) (where T(c) approximately M(-alphaFe) and M is the iron isotope mass); i.e., the sample containing the large iron isotope mass depicts a higher T(c). Systematic inverse shifts in T(c) were clearly observed between the samples using thr...

The asymmetric unit of the title compound, [Fe(2)(C(5)H(9)O(2))(4)(C(6)H(7)N)(2)], contains one unique Fe-atom site located close to a centre of symmetry which generates the mol-ecular dimer. The two Fe atoms are bridged by four carboxyl-ate groups and are each coordinated by a mol-ecule of 2-picoline. Electron counting and the 18-electron rule suggest that a chemical single bond is likely to e...