The influence of crystallite size on the adsorption reactivity of phosphate on 2-line to 6-line ferrihydrites was investigated by combining adsorption experiments, structure and surface analysis, and spectroscopic analysis. X-ray diffraction (XRD) and transmission electron microscopy (TEM) showed that the ferrihydrite samples possessed a similar fundamental structure with a crystallite size var...

The maintenance of waterways generates large amounts of dredged sediments, which are deposited on adjacent land surfaces. These sediments are often rich in metal contaminants and present a risk to the local environment. Understanding how the metals are immobilized at the molecular level is critical for formulating effective metal containment strategies such as phytoremediation. In the present w...

Biogeochemical transformation (inclusive of dissolution) of iron (hydr)oxides resulting from dissimilatory reduction has a pronounced impact on the fate and transport of nutrients and contaminants in subsurface environments. Despite the reactivity noted for pristine (unreacted) minerals, iron (hydr)oxides within native environments will likely have a different reactivity owing in part to change...

High levels of arsenic in groundwater and drinking water are a major health problem. Although the processes controlling the release of As are still not well known, the reductive dissolution of As-rich Fe oxyhydroxides has so far been a favorite hypothesis. Decoupling between arsenic and iron redox transformations has been experimentally demonstrated, but not quantitatively interpreted. Here, we...

Introduction: Isheyevo, a metal-rich CH/CB-like meteorite, shows whole-rock δ 15 N enrichment up to ~+1500‰ [1]. Bonal et al. discovered rare chondritic clasts in Isheyevo containing mafic silicates, large bulk 15 N enrichments (δ 15 N from +1000 to 1300‰) and µm-sized " hotspots " with δ 15 N approaching +5000‰ [2,3]. The source of these high 15 N enrichments, whether due to molecular cloud, n...

In a high mountain lake and catchment area, a natural process of phosphorus enrichment is observed, induced by the iron-cycle. Investigations focus on the speciation of P and Fe in iron and manganese rich oxidic mineral crusts formed at the surface of rock pebbles. Iron and phosphorus are spatially associated although they are not forming iron phosphate minerals. While Fe and P K edge XAS spect...