نتایج جستجو برای: free energy of electron transfer
تعداد نتایج: 21330973 فیلتر نتایج به سال:
Light-induced diffusion-controlled electron transfer is proposed as an underlying mechanism for the intermittency (power law and breakdown) of a single quantum dot and ensemble-averaged fluorescence decay. The intensity decay can be approximated to a stretched exponential expression. The physical links to the free energy gap, reorganization energy, electronic coupling, and diffusion correlation...
The X-ray Pump-Probe instrument achieves femtosecond time-resolution with hard X-ray methods using a free-electron laser source. It covers a photon energy range of 4-24 keV. A femtosecond optical laser system is available across a broad spectrum of wavelengths for generating transient states of matter. The instrument is designed to emphasize versatility and the scientific goals encompass ultraf...
This work develops a Monte Carlo (MC) simulation method for calculating the heat generation rate in electronic nanostructures. Electrons accelerated by the electric field scatter strongly with optical phonons, yet heat transport in silicon occurs via the faster acoustic modes. The MC method incorporates the appropriate energy transfer rates from electrons to each phonon branch. This accounts fo...
The interpretation of the results of this paper were based on electromagnetic fields that do not satisfy Maxwell’s equations and neglect the small but important longitudinal electric field near a focus. The intricate question of vacuum laser acceleration of free electrons deserves more rigorous analysis. The experimental results presented by Malka et al. address an issue that has been debated w...
In the report "Free energy and temperature dependence of electron transfer at the metal-electrolyte interface" by C. E. D. Chidsey (22 Feb., p.919), the axis label in figure 3B should have been "Time (s)," not "Time (ms)." Also, the text following equation 8 should have read, "where C = [See equation in the PDF file]
Renewable resource of carbon-free energy is crucial in the current scenario of global warming and our growing energy needs. Besides, the significance of safer energy resources has been underscored by many nuclear mishaps, including the recently crippled Fukushima Nuclear power plant in Japan. Sunlight is the most promising alternative to nuclear fuels and greenhouse-gas-emitting fossil and alco...
The kinetics of photoinduced electron-transfer (ET) reactions have been measured in a series of synthetic donor-acceptor complexes. The electron donors are singlet or triplet excited iridium(I) dimers (Ir(2)), and the acceptors are N-alkylpyridinium groups covalently bound to phosphinite ligands on the Ir(2) core. Rate constants for excited-state ET range from 3.5 x 10(6) to 1.1 x 10(11) per se...
Electron-transfer rate constants were determined by means of lifetime measurements for the fluorescence quenching of 9,10-dicyanoanthracene by aromatic amines and methoxybenzenes as electron donors, and for the quenching of the synthetic dyes eosin Y and phenosafranine by a series of p-benzoquinones as electron acceptors. All determinations were carried out in acetonitrile at 298 K. The quenchi...
نمودار تعداد نتایج جستجو در هر سال
با کلیک روی نمودار نتایج را به سال انتشار فیلتر کنید