Journal:
:Journal of materials chemistry. A, Materials for energy and sustainability2021
A series of nine polymers intrinsic microporosity (PIMs) derived from different bis-catechol monomers and 2,3,7,8-tetrafluoro-5,5′,10,10′-tetraoxidethianthrene (TOT) were synthesised tested for their potential use as gas separation membranes.
Bowen YaoSalvatore MandràJohn O CurryShamil ShaikhutdinovHans-Joachim FreundJoshua Schrier
Membrane-based gas separation processes can address key challenges in energy and environment, but for many applications the permeance and selectivity of bulk membranes is insufficient for economical use. Theory and experiment indicate that permeance and selectivity can be increased by using two-dimensional materials with subnanometer pores as membranes. Motivated by experiments showing selectiv...