We investigated the orientation and morphology of Cu nanoparticles grown under ultrahigh-vacuum conditions on ZnO(0001), ZnO(0001̅), ZnO(101̅4) single crystal surfaces by scanning tunneling microscopy, high-energy grazing incidence X-ray diffraction, low-energy electron microscopy. The (111) oriented NPs basal ZnO showed only small area fractions high indexed Cu(225) Cu(331) facets. show alignmen...

3-Dialkylaminomethyl substituted salicylaldoximes are efficient metal salt extractants, and, in contrast to related "salen"-based reagents, are sufficiently stable to acid hydrolysis to allow commercial application in base metal recovery. Crystal structures show that metal salts are bound by a zwitterionic form of the reagents, with copper(II) nitrate, tetrafluoroborate and trifluoroacetate for...

The experiment was set up in the greenhouse of Faculty Agriculture, University Belgrade with aim investigating potential perennial ryegrass (Loliumperennial L.) to grow on substrates exceptionally unfavorable characteristics. Tailings, characterized by very poor physical and chemical properties deficiency nutrients were used as substrate. research examined effects three different fertilizers tw...

Copper (Cu) and cholesterol (Cho) are both associated with neurodegenerative illnesses in humans and animals models. We studied the effect in Wistar rats of oral supplementation with trace amounts of Cu (3 ppm) and/or Cho (2%) in drinking water for 2 months. Increased amounts of nonceruloplasmin-bound Cu were observed in plasma and brain hippocampus together with a higher concentration of cerul...

a simple and reproducible method for the rapid extraction and determination of trace amounts of copper(ii) ions using octadecyl-bonded silica membrane disks modified by 1-(2-pyridyl azo)2-naphtol(pan) and atomic absorption spectrometry was presented. the method was based on complex formation on the surface of the envi-18 disk tm disks followed by stripping of the retained species by minimum amo...

Sulfate-reducing bacterial biofilms were grown in continuous culture. When exposed to medium containing 20 or 200 microM Cu, biofilms accumulated Cu. Energy-dispersive X-ray analysis (EDXA) showed that accumulation of Cu occurred in the form of sulfides while EDXA mapping of Cu and S in biofilm sections indicated that they were not uniformly distributed but located in the surface of the biofilm...

With the aim of developing a computationally inexpensive method for modeling the high-temperature reaction dynamics of transition metal catalyzed reactions we have developed a ReaxFF reactive force field in which the parameters are fitted to a substantial quantum mechanics (QM) training set, containing full reaction pathways for relevant reactions. In this paper we apply this approach to reacti...

High-strength low-carbon ferritic steels attaining a maximum yield strength of 1600 MPa by combined Cu and NiAl precipitationstrengthening were developed. The yield strength of the alloys increases monotonically with the total concentration of the principal alloying elements i.e. Mn, Cu, Ni and Al. At 12.40 at.%, a 1600 MPa yield strength is achieved after solution treatment at 950 C followed b...

A batch experiment was conducted to compare the Cu scavenging capacity between two different red mud types: the first one was a highly basic red mud derived from a combined sintering and Bayer process, and the second one was a seawater-neutralized red mud derived from the Bayer process. The first red mud contained substantial amounts of CaCO3, which, in combination with the high OH activity, fa...