High pressure and low temperature experiments with CO(2) hydrate were performed using diamond anvil cells and a helium-refrigeration cryostat in the pressure and temperature range of 0.2-3.0 GPa and 280-80 K, respectively. In situ x-ray diffractometry revealed that the phase boundary between CO(2) hydrate and water+CO(2) extended below the 280 K reported previously, toward a higher pressure and...

Based on driving force for crystallization of one-component gas hydrate, in this report an expression for the supersaturation for crystallization of multicomponent gas hydrate is derived. Expressions for the supersaturation are obtained in isothermal and isobaric regimes. The results obtained are applied to the crystallization of hydrates of mixtures of methane plus ethane and can apply to ...

Natural gas hydrates (NGHs) are efficient and promising energy resources because of their high density. In addition, NGH occurs in sediments under certain pressure temperature conditions has the potential to meet increasing global demand. However, exploitation requires a precise characterization understanding hydrate formation, accumulation, dissociation mechanisms. this context, microstructura...

[1] The interaction among water molecules, guest gas molecules, salts, and mineral particles determines the nucleation and growth behavior of gas hydrates in natural sediments. Hydrate of tetrahydrofuran (THF) has long been used for laboratory studies of gas hydrate-bearing sediments to provide close control on hydrate concentrations and to overcome the long formation history of methane hydrate...

The paper develops the Life Origination Hydrate Hypothesis (LOH-hypothesis), according to which living-matter simplest elements (LMSEs, which are N-bases, riboses, nucleosides, nucleotides), DNA- and RNA-like molecules, amino-acids, and proto-cells repeatedly originated on the basis of thermodynamically controlled, natural, and inevitable processes governed by universal physical and chemical la...

We present molecular dynamics simulation evidence of spontaneous formation of quasi-one-dimensional (Q1D) hydrogen gas hydrates within single-walled carbon nanotubes (SW-CNTs) of nanometer-sized diameter (1-1.3 nm) near ambient temperature. Contrary to conventional 3D gas hydrates in which the guest molecules are typically contained in individual and isolated cages in the host lattice, the gues...

Iron oxide (Fe2O3) is widely used as a catalyst, pigment and gas sensitive material.  In this article, α-Fe2O3 nano-rods were first synthesized via a simple chemical method using iron(III) nitrate 9- hydrate (Fe(NO3)3.9H2O) as precursor. XRD pattern showed that the iron oxide nanoparticles exhibited alpha-Fe2O3 (hematite) structure in nanocrystals. The single-phase α- Fe2O3 nano-rods were prepa...

Paleooceanographic evidence has been used to postulate that methane from oceanic hydrates may have had a significant role in regulating global climate, implicating global oceanic deposits of methane gas hydrate as the main culprit in instances of rapid climate change that have occurred in the past. However, the behavior of contemporary oceanic methane hydrate deposits subjected to rapid tempera...