The wetting of the planar interface between air saturated with octane vapor and an aqueous solution by octane is investigated by ellipsometry and interfacial tension measurements. The interfacial interactions are varied through the concentration of the uncharged solute (glucose). We observe abrupt and continuous increases of the octane coverage with growing solute concentration. This we attribu...

In this paper we review simulation and experimental studies of thermal capillary wave fluctuations as an ideal means for probing the underlying disjoining pressure and surface tensions, and more generally, fine details of the Interfacial Hamiltonian Model. We discuss recent simulation results that reveal a film-height-dependent surface tension not accounted for in the classical Interfacial Hami...

2014 The interfacial properties of a system of molten polymers at a temperature just below the critical temperature of demixing are studied in the framework of a mean field theory. The properties of the interface are very specific, the interface is much larger than those of usual binary liquids and the interfacial tension is much smaller so that only optical methods will permit experimental stu...

The effect of a uniform electric field on the bulk and interfacial properties of a model dipolar fluid is investigated by using a modified mean-field density functional theory. Particular attention is given to the dependence of the vapor-liquid phase coexistence in a slab-shaped system on the direction of the electric field with respect to the slab surfaces, as well as in the sphere-shaped syst...

We present the results of laboratory experiments that quantify the physical controls on the thickness of the falling film of liquid around a Taylor bubble, when liquid–gas interfacial tension can be neglected. We find that the dimensionless film thickness l′ (the ratio of the film thickness to the pipe radius) is a function only of the dimensionless parameter Nf = r √ gD3/m, where r is the liqu...