Recently, we reported a novel access to 2,2-diethyl-3-[(E/Z)-prop-1-en-1-yl]cyclobutanone by an intramolecular nucleophilic substitution with allylic rearrangement (S(N)i') of (E)-6-chloro-3,3-diethylhept-4-en-2-one. The ring closure reaction was found to proceed with selective syn-displacement of the leaving group. This method was now applied to the total synthesis of junionone, an olfactorily...

Your use of the JSTOR archive indicates your acceptance of JSTOR's Terms and Conditions of Use, available at http://www.jstor.org/page/info/about/policies/terms.jsp. JSTOR's Terms and Conditions of Use provides, in part, that unless you have obtained prior permission, you may not download an entire issue of a journal or multiple copies of articles, and you may use content in the JSTOR archive o...

Seven previously undescribed diaporthalean species were found in eastern Asia and eastern North America. Three of these new species and one previously known species are assigned to a new genus Leucodiaporthe. Descriptions and illustrations are provided for the new taxa including Allantoporthe leucoth6es sp. nov., Diaporthella corylina sp. nov., Leucodiaporthe acerina sp. nov., L. juglandis sp. ...

Projectile weapons (i.e. those delivered from a distance) enhanced prehistoric hunting efficiency by enabling higher impact delivery and hunting of a broader range of animals while reducing confrontations with dangerous prey species. Projectiles therefore provided a significant advantage over thrusting spears. Composite projectile technologies are considered indicative of complex behavior and p...

The history of Eastern African hominids has been linked to a progressive increase of open grassland during the past 8 million years. This trend was explained by global climatic processes, which do not account for the massive uplift of eastern African topography that occurred during this period. Atmosphere and biosphere simulations quantify the role played by these tectonic events. The reduced t...

We study the global spatio-temporal patterns of influenza dynamics. This is achieved by analysing and modelling weekly laboratory confirmed cases of influenza A and B from 138 countries between January 2006 and January 2015. The data were obtained from FluNet, the surveillance network compiled by the the World Health Organization. We report a pattern of skip-and-resurgence behavior between the ...

This article draws a comparison between two adjacent ethnic groups, namely the Ainu of Hokkaido and the Nivkh of Sakhalin. We shall follow the historical development of the border areas between Japan and Russia and describe the prevailing situation of these aboriginal peoples on both sides of the border. The legal measures taken by the Japanese government for the promotion of Ainu culture and t...

The Pleistocene and recent distributions of the taxa are discussed. A new variety of Juniperus ashei, J. ashei Buch. var. ovata R. P. Adams is recognized from west Texas and northern Mexico. It differs from typical J. ashei in having whip leaf glands that are oval to elongate rather than hemispherical, smaller female cones, smaller seeds and more seeds per cone. In addition, the leaf oil of var...

A new lignan glycoside, named juniperigiside (1) was isolated from the CHCl(3) soluble fraction of the MeOH extract of stems and leaves of Juniperus rigida S.et Z. Compound 1 was identified by 1D- and 2D-NMR spectroscopy as well as CD analysis as (2R,3S)-2,3-dihydro-7-methoxy-2-(4'-hydroxy-3'-methoxyphenyl)-3-hydroxymethyl-5-benzofuranpropanol 4'-O-(3-O-methyl)-α-L-rhamnopyranoside. Five known ...