A new zeolite catalyst, Al-RUB-41, was synthesized for the first time. It was tested as a catalyst in methanol amination, and showed a shape-selective performance that results in a highly favorable product distribution. The shape-selective nature was also evidenced by using Pt-Al-RUB-41 as a bifunctional catalyst for decane hydroconversion. With its unique pore architecture and remarkable shape...

In this paper we review molecular modeling investigations of polymer/layered-silicate intercalates, as model systems to explore polymers in nanoscopically confined spaces. The atomic-scale picture, as revealed by computer simulations, is presented in the context of salient results from a wide range of experimental techniques. This approach provides insights into how polymeric segmental dynamics...

A highly tough and transparent film material was prepared from synthetic saponite (SPN) nanoplatelets of low aspect ratios and nanofibrillar cellulose. The nanofibrillar cellulose was chemically modified by topological surface oxidation using 2,2,6,6-tetramethylpiperidinyl-1-oxyl (TEMPO) as a catalyst. Both synthetic SPN nanoplatelets and TEMPO-oxidized cellulose nanofibrils (TOCNs) have abunda...

In this study, the reinforcement of ultrahigh-molecular-weight polyethylene (UHMWPE) with biotite was investigated. The biotite filler was mechanically activated with different dry surfactants to improve its compatibility with UHMWPE and decrease agglomeration among biotite particles. Alkyldimethylbenzylammonium chloride (ADBAC) and cetyltrimethylammonium bromide (CTAB) were selected as cationi...

Self-assembled layers of alkyl chains grafted onto the surfaces of layered silicates, metal, and oxidic nanoparticles are utilized to control interactions with external media by tuning the packing density of the chains on the surface, head group functionality, and chain length. Characterization through experiment and simulation shows that the orientation of the alkyl layers and reversible phase...

This study aims to assess the viability of nanocomposites in fused filament fabrication. Polylactide/organo-modified layered silicate materials have been studied terms structure and properties evolution through whole manufacturing chain, for thermomechanical optimisation. The method included optimisation by composite formulation additive process experimental designs. A competition between flow ...

In the field of genetic research and the subsequent rise of biobanks an intensive discussion is taking place on national and international levels about property and personality rights to one’s own body and body parts. The authors attempt to develop on the basis of the current controversially discussed law a concept of property, which can solve the legal and bioethical problems of the multiple u...

in this study, rice husk and sodium silicate solution were used to produce particleboards. sodium silicate was used as bonding aid by 25, 20, 15, 10, 5 and zero percent (based on rice husk dry weight). to modify the mechanism of bondability, one percent of 4,4’-diphenylmethane diisocyanate (mdi) was added for every five percent less sodium silicate solution. the effect of diisocyanate on bondab...