A novel method for the in situ generation of catalytically active small metal nanoparticles, by anion extrusion on a parent porous copper chloropyrophosphate framework, has been developed to generate gold, platinum and palladium nanoparticles for sustainable catalytic oxidations using molecular oxygen as the oxidant. Transmission electron microscopy coupled with detailed structural and physico-...

Group I and II metal amidoboranes have been identified as one of the promising families of materials for efficient H(2) storage. However, the underlying mechanism of the dehydrogenation of these materials is not well understood. Thus, the mechanisms and kinetics of H(2) release in metal amidoboranes are investigated using high level ab initio calculations and kinetic simulations. The metal play...

Heavy metal concentrations were examined in surface sediments from 79 sites within the Altata-Ensenada del Pabellon lagoon system. Data were normalized to separate natural from anthropogenic factors using aluminum and lithium as conservative elements and following two different discriminating criteria. For the normalization process, the natural metal concentrations were assumed to vary consiste...

In this study, we investigated the atmospheric heavy metal concentrations in the particulate matter inside the subway stations of Seoul. In particular, we examined the correlation between the heavy metals and studied the effect of the heavy metals on cell proliferation. In six selected subway stations in Seoul, particulate matter was captured at the platforms and 11 types of heavy metals were a...

– The metal-insulator transition (MIT) of the Magnéli phase V4O7 is studied by means of electronic structure calculations using the augmented spherical wave method. The calculations are based on density functional theory and the local density approximation. Changes of the electronic structure at the MIT are discussed in relation to the structural transformations occuring simultaneously. The ana...

Effects were studied of 200 ppm silver and copper nano-suspensions, with size range from 20 to 80 nm, on the hardness of particleboards produced at an industrial scale at the Iran-Choob Factory, Iran. Metal nano-suspensions were added to the mat at two levels of 100 and 150 milli-liters/kg dry weight wood particles, and the results were compared with those of the control panels. Results showed ...

The underlying mechanism behind the metal-to-insulator transition in ${\mathrm{VO}}_{2}$ is still a topic of intense debate. two leading theoretical interpretations associate with either electron-lattice or electron-electron correlations. Novel experimental results are required to converge towards one scenarios. Here we report on temperature-dependent angle-resolved photoelectron study thin fil...