In this study, two Ru/TiO2 samples with different TiO2 facets were prepared to investigate their photo-thermal catalytic CO2 + H2 reaction behavior. Without UV irradiation, the 67% {001} facet (3RT) displayed improved thermal activity for methanation than that of 30% (0RT). After pretreatment, both exhibited enhanced activities, but H2-treated 3RT (3RT-H) superior 0RT (0RT-H). Under 3RT-H appar...