In this study, novel photocatalyst monolith materials were successfully fabricated by a non-solvent induced phase separation (NIPS) technique. By adding a certain amount of ethyl acetate (as non-solvent) into a cellulose/LiCl/N,N-dimethylacetamide (DMAc) solution, and successively adding titanium dioxide (TiO2) nanoparticles (NPs), cellulose/TiO2 composite monoliths with hierarchically porous s...

Computational fluid dynamic (CFD) modeling of full-scale catalytic converters with realistic chemistry has remained elusive primarily due to the extreme computational requirements. In this work, a new low-memory coupled implicit solver, based on the conservative unstructured finite-volume method, was utilized to simulate laboratory-scale catalytic converters with implicit coupling between fluid...

Polymer microfluidic chips employing in situ photopolymerized polymethacrylate monoliths for high-performance liquid chromatography separations of peptides is described. The integrated chip design employs a 15 cm long separation column containing a reversed-phase polymethacrylate monolith as a stationary phase, with its front end seamlessly coupled to a 5 mm long methacrylate monolith which fun...

Magnesium nickel silicate (MNS) has been investigated as a catalyst to convert tars and light hydrocarbons to syngas (CO and H2) by steam reforming and CO2 reforming in the presence of H2S for biomass gasification process at NexTech Materials. It was observed that complete CH4 conversion could be achieved on MNS catalyst granules at 800–900 °C and a space velocity of 24,000 mL/g/h in a simulate...

Equipment Scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX) were performed with a Crossbeam 1540 XB electron microscope to probe the morphological dry-state properties of the prepared materials and existence of desirable chelated palladium functionality. Liquid chromatographic measurements were performed with a 1290 Infinity UHPLC instrument from Agilent Technolo...

Although the evidence for neutrino oscillation is growing year after year, the final proof that the observed anomalies are due to oscillation is still outstanding. Alternative models (neutrino decay, potential decoherence effect, influence of large extra-dimensions) to explain the SuperKamiokande (SK) atmospheric neutrinos results have been proposed. On the experimental side, as pointed out als...

In this study, we described a simple and effective modification procedure to prepare poly (methacrylate-co-ethylene glycol dimethacrylate) monolithic columns functionalized with 3-aminophenylboronic acid. The column morphology, pore size and specific surface area of the fabricated monolith were characterized by scanning electron microscopy, X-ray photoelectron spectroscopy, thermogravimetric an...

The objective of this work is to evaluate a novel regenerable sorbent for mercury capture based on gold nanoparticles supported on a honeycomb structured carbon monolith. A new methodology for gold nanoparticles deposition onto carbon monolith support has been developed to obtain an Au sorbent based on the direct reduction of a gold salt onto the carbon material. For comparison purposes, colloi...

A novel organic monolithic stationary phase was prepared for high-performance liquid chromatography (HPLC) by in situ copolymerization. In which, triallyl isocyanurate (TAIC) and trimethylolpropane triacrylate (TMPTA) in a binary porogenic solvent consisting of polyethylene glycol 200 and 1, 2-propanediol were used. The resultant monoliths with different column properties (e.g., morphology and ...

Vacuum-induced surface freezing has been used to produce uni-directional freezing of colloidal aluminum oxide dispersions. It leads to zones of different structure within the resulting sintered monoliths that are highly similar to those known for freeze casting using a cryogen cold source. A more-or-less dense surface layer and a cellular sub-surface region are formed, beneath which is a middle...