During the past few decades molecular dynamics has been a widely applied tool to simulate fluid confined in micro/nano geometries. What makes interfacial fluids fundamentally different from the bulk fluid is the fact that their density varies considerably over microscopic distances. A class of such strongly inhomogeneous fluids are fluids confined in very narrow channels by solid boundaries. In...

W e investigate electrolyte-mediated interactions of charged analyte particles confined within nanochannels. We investigate how the free energy of analyte particle position varies with ionic strength and ion valence for multivalent 2:1 electrolytes and monovalent 1:1 electrolytes. Our studies use a particle-based Restrictive Primitive Model (RPM), classical Density Functional Theory (cDFT), and...

We demonstrate an ion pump, consisting of a nanochannel with an AC driven asymmetric electrode array. Our system enables us to actively pump ions using a low driving voltage. In all experiments the electrical double layers are overlapping. Via viscous coupling ion pumping is accompanied by liquid pumping. Actuation below 500 mV at 10 Hz results in a liquid velocity of ~10 μm/s, corresponding to...

We demonstrate the fabrication and operation of an integrated device containing a nanoelectromechanical system and an integrated detector. This on-chip silicon nanochannel field effect transistor is used to measure the motion of a silicon nanomechanical resonator at room temperature. Furthermore, we describe the operation of the device as a silicon-based room-temperature on-chip amplifier for i...

The elastic properties of the nanotubes of self-assembled aromatic dipeptide diphenylalanine are investigated by means of Raman spectroscopy and a mass-in-mass 1D model. Analysis of nanotubes' lattice vibrations reveals the essential contribution of the water in the nanochannel core of the tubes to the Young's modulus and high water mobility along the channel. Direct measurements of the Young's...