in this research we used heavy propylene tetramer (hpt) and a1c13 —bf3 (lewis acids) ascatalyst and ethanol, n-propanol and n-butanol as co-catalyst. using lewis acids as catalyst, thehpts form molecules with higher molecular weight. since the raw materials of the reaction are byproducts of other reactions, are not pure and contain various compounds with different m.w andalso different chemical...

a linear low density polyethylene (lldpe) production process, including two- fuidized bed reactors in series (fbrs) and other process equipment, was completely simulated by aspen polymer plus software. fluidized bed reactors were considered as continuous stirred tank reactors (cstr consisted of polymer and gas phases). poly-srk and nrtl-rk equations of state were used to describe polymer and no...

in this article, a complete model for the mixed flow slurry reactor for polymerization of ethylene to high density polyethylene in the presence of ziegler-natta catalyst is presented. in addition to the effects of the multiple active sites, the effect of other important parameters such as the catalyst concentration, co-catalyst, hydrogen, monomer, impurities and pressure on the mass-average and...

the potential of carbon nanotubes (cnt) supported cobalt catalysts for fischer-tropsch (ft) reaction is shown. using the wet impregnation method cobalt on carbon nanotubes catalysts were prepared with cobalt loading varying from 15 to 45 wt. %. the catalysts are characterized by different methods including: bet physisorption, x-ray diffraction, hydrogen chemisorption, and temperature-programmed...

1,5-benzodiazepines are regarded as one of the most important classes of heterocyclic compounds as privileged structures and have vast range of applications in the field of medicine and chemistry. they are therefore attractive synthetic targets for organic and medicinal chemist. the current review article mainly covers the multicomponent green chemistry approaches for the synthesis of 1,5-benzo...

Heterogeneous catalysts are promising for the transesterification reaction of vegetable oils to produce biodiesel and have been studied intensively over the last decade. Unlike the homogeneous catalysts, heterogeneous catalysts can be easily separated from reaction mixture and reused for many times. They are environmentally benign and could be easily operated in continuous processes. This revie...

Highly electron deficient scandocene derivatives of the types (q5-CsMe&ScR, {(q5-CsMe4)2SiMe2}ScR and {(q5-C5H3CMe3)2SiMe2}ScR catalyze the polymerization of ethylene, the head-to-tail dimerization of a olefins, the cyclization of a,w dienes to meth lene cycloalkanes, and the branching of 1,4 pentadienes to isoprenes. The mechanisms oythe individual steps have been studied. Key steps involve se...