a rapid, simple and sensitive high-performance liquid chromatography method was developed for determination of ciprofloxacin in plasma by means of ultraviolet detection. ofloxacin was used as an internal standard and separation carried on a novapak c18 column using a mobile phase of 0.01 m phosphate buffer (ph =2.6): methanol (82: 18 v/v). extraction of drug was performed from plasma by liquid-...

the present article reports on the application of modified organo nanoclay as a green, easily prepared and stable solid sorbent for the preconcentration of trace cobalt ion in aqueous solution. the organo nanoclay was modified by adsorption of 5-(4-dimethyl amino-benzylidene) rhodanin reagent onto it. the sorption of co2+ ions was quantitative in the ph range of 7.0 to 8.5, whereas quantitative...

Two novel 1D coordination chains containing the curcuminoid (CCMoid) ligand 9Accm have been characterized: [Co(9Accm)2(4,4 ́-bpy)]n (1) and [Ni(9Accm)2(4,4 ́-bpy)]n (2). The two compounds were synthesized by solvothermal and microwave (MW) assisted techniques, respectively, and crystals of both systems were directly obtained from the mother solutions. Crystal structures of 1 and 2 prove that both...

Presented herein is a study of the acid-induced demetalation of two sterically hindered copper corroles, Cu β-octabromo-meso-triphenylcorrole (Cu[Br8TPC]) and β-octakis(trifluoromethyl)-meso-tris(p-methoxyphenyl)corrole (Cu[(CF3)8TpOMePC]). Unlike reductive demetalation, which affords the free-base β-octabromocorrole, demetalation of Cu[Br8TPC] under non- reductive conditions (CHCl3/H2SO4) resu...

Crystallization from an aqueous methanol system composed of Ni(NO3)2, 2,2'-bipyridine (bpy) and LiTCNQ (TCNQ is 7,7,8,8-tetra-cyano-quinodi-methane) in a 1:3:2 molar ratio yielded single crystals of bis-[tris-(2,2'-bi-pyridine-κ2N,N')nickel(II)] bis-(7,7,8,8-tetra-cyano-quinodi-methane radical anion) bi[7,7,8,8-tetra-cyano-quino-dimethanide] hexa-hydrate, [Ni(C10H8N2)3]2(C24H8N8)(C12H4N4)2·6H2O...

The stage-specific spatial distribution and mortality of Balanus glandula and Chthamalus spp. larvae were assessed with a series of daily vertical plankton tows collected from innershelf waters in La Jolla, Southern California, in March 2003. Sampling stations were located within 1.1 km of the shoreline, at depths of 10 to 45 m. For both groups, we observed a spatial segregation of naupliar sta...

ISO spectra 1 of the supernova remnant RCW103 are presented. This object is the prototype of a SNR shock heavily interacting with dense ISM (probably a molecular cloud). The spectra are dominated by prominent lines and show very little continuum at < 40 m suggesting that the 12 and 25 m IRAS emission from these types of remnant could be dominated by lines rather than continuum emission from war...

ISO spectral observations of the supernova remnant RCW103 are presented. This object is the prototype of relatively young remnants ( 103 yr) with fast shocks (vs 1000 km/s) interacting with dense interstellar medium. The spectrum is dominated by prominent lines of [NeII], [SiII], [FeII] and other low excitation species which provide, for the first time, a simple and reliable estimate of the gas...

We report spectroscopic observations of the nova M31N-2007-06b, which was found to be spatially coincident with the M31 globular cluster Bol 111. This nova is the first out of more than 700 discovered in M31 over the past century to be associated with one of the galaxy’s globular clusters. A total of three spectra of the nova were obtained 3, 6, and 36 days post discovery. The data reveal broad...

Producing reliable electrical contacts of molecular dimensions has been a critical challenge in the field of molecule-based electronics. Conventional thin film deposition and photolithography techniques have been utilized to construct novel nanometer-sized electrodes on the exposed vertical plane on the edge of a thin film multilayer structure (metal/insulator/metal). Via thiol surface attachme...