The ability to determine the pyrrolic nitrogen compounds, which present in trace quantities in oils, exhibit changes in both absolute and relative concentrations that correlate with migration distance. Such molecules appear promising as empirical but quantitative indicators of the relative distances of oils and present a first step towards true source to oil reservoir distance indicators. Quant...

The important developments in industrial fermentation lead to the utilization of microbial enzymes in different applications. Selected organisms Aspergillus fumigatus, A. terreus, Penicillium chrysogenum, P. funiculosum and Fusarium moniliforme. Various environmental parameters like pH, temperature and nutritional parameters such as carbon and nitrogen sources were investigated to optimize the ...

The copper-catalyzed α-amination of carbonyl compounds using nitrosoformate intermediates as the electrophilic source of nitrogen is reported. The reaction merges aerobic oxidation and Lewis acid catalysis. The scope of the reaction is broad in terms of both the N-substituted hydroxylamines and the β-ketoesters. The new methodology harnesses the power of nitrosoformate intermediates and demonst...