نتایج جستجو برای: oxidation of sulfides
تعداد نتایج: 21171920 فیلتر نتایج به سال:
gol-e-gohar iron ore mine of sirjan in southern part of iran is a large open pit that operates below the groundwater table and during mining operation, dewatering is required to prevent operation processes from flooding. current operation is going on by digging wells in or out of the pit and pumping to prevent flooding. as a result of the former dewatering operation a vast deep cone of depressi...
The Mafic complex of Mishow is exposed in the north-western part of Iran, in the East Azerbaidjan Province (SW of Marand). Two different types of mineralization, sulphides and oxides, occur in the intrusion complex. The sulphide ore bodies are mainly composed of pyrrhotite accompanied by chalcopyrite, pentlandite, sphalerite, pyrite and troilite. The oxides mineralization consists of ilmenite a...
The 4-hydroxyacetophenone monooxygenase (HAPMO) from Pseudomonas fluorescens ACB catalyzes NADPH- and oxygen-dependent Baeyer-Villiger oxidation of 4-hydroxyacetophenone to the corresponding acetate ester. Using the purified enzyme from recombinant Escherichia coli, we found that a broad range of carbonylic compounds that are structurally more or less similar to 4-hydroxyacetophenone are also s...
Palladium-catalyzed carbothiolation of terminal alkynes with azolyl sulfides affords various 2-(azolyl)alkenyl sulfides with perfect regio- and stereoselectivities. The present addition reaction proceeded through a direct cleavage of carbon-sulfur bonds in azolyl sulfides. The resulting adducts that are useful intermediates in organic synthesis are further transformed to multisubstituted olefin...
HPLC, Methylene Sulfides, Methylene Selenides, Selenium Sulfides, Sulfur Heterocycles The Separation of a number of cyclic methylene sulfides and selenides by reversed-phase high-pressure liquid chromatography is reported. The retention times as well as the capacity factors depend in a systematic way on the ring size, the number and kind of chalcogen atoms, and the number of heteronuclear bonds...
Fumarate and nitrate reduction (FNR) regulatory proteins are O(2)-sensing bacterial transcription factors that control the switch between aerobic and anaerobic metabolism. Under anaerobic conditions [4Fe-4S](2+)-FNR exists as a DNA-binding homodimer. In response to elevated oxygen levels, the [4Fe-4S](2+) cluster undergoes a rapid conversion to a [2Fe-2S](2+) cluster, resulting in a dimer-to-mo...
Recently we showed that visible-UV spectra in aqueous solution can be accurately calculated for arsenic (III) bisulfides, such as As(SH)3, As(SH)2S 2 and their oligomers. The calculated lowest energy transitions for these species were diagnostic of their protonation and oligomerization state. We here extend these studies to As and Sb oxidation state III and V sulfides and to polysulfides Sn , n...
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