No Hung0356 A P-XANES Study of Phosphate Sorption to Gibbsite and Calcium Carbonate S. Hunger, K.E. Staats, and D.L. Sparks (U. of Delaware) Beamline: X19A Introduction. Sorption and precipitation reactions of phosphate in soils are of interest as they determine phosphate mobility and bioavailability. Soils, which have continuously received P fertilizers over decades or centuries, can act as no...

Phosphorous is going to be plant nutrient that will limit the agricultural production in the next millennium. It is a major growth-limiting nutrient, and unlike the case of nitrogen, there is no large atmospheric source that can be made biologically available (Ezawa et al., 2002). As regards the role of P, it stimulate root development and growth, gives plant rapid and vigorous start leading to...

Rechargeable aqueous metal-ion batteries made from non-flammable and low-cost materials offer promising opportunities in large-scale utility grid applications, yet low voltage and energy output, as well as limited cycle life remain critical drawbacks in their electrochemical operation. Here we develop a series of high-voltage aqueous metal-ion batteries based on 'M(+)/N(+)-dual shuttles' to ove...

In this work, we investigate the crystal chemistry of Fe/V-mixed NASICON [sodium (Na) Super Ionic CONductor] compositions Na3FeV(PO4)3 and Na4FeV(PO4)3 that are structurally related to Na3V2(PO4)3, a positive electrode for Na-ion batteries. To synthesize Na4FeV(PO4)3, various synthesis routes (solid-state, sol–gel-assisted, electrochemical syntheses) were investigated. Direct syntheses resulted...

Argon oxygen decarburisation (AOD) slag may be used for phosphorus (P) removal, as its high pH and weatherable calcium (Ca) minerals provide sufficient Ca(2+) and OH(-) for calcium phosphate (Ca-PO4) precipitation. This study examined the P removal performance of AOD slag for use as wastewater treatment material. Batch experiments were carried out using both synthetic P solution and real wastew...