Over the past decade much information has been published on the analysis of organics extracted from treated water. Certain of these organics have been shown to be by-products of the chlorination disinfection process and to possess harmful effects at high concentrations. This has resulted in increased interest in alternative disinfection processes, particularly ozonation. The data on organics ha...

Leachate pollution is one of the main problems in landfilling. Among the most problematic parameters in stabilized leachate are COD, ammonia, and color. The treatment technology that can be used may differ based on the type of leachate produced. Even after treatment, the effluent characteristics are always hard to comply with the discharge standard. Ozonation is one of the chemical processes th...

Catalytic membrane ozonation is a hybrid process that combines filtration and catalytic ozonation. The deposited with an appropriate solid material acts as catalyst. As consequence, the contactor can act simultaneously (i.e., improving transfer/dissolution of gaseous ozone into liquid phase), well reactor oxidizing organic compounds). It be used in water wastewater treatment limiting disadvanta...

Pharmaceutical products have become a necessary part of life. Several studies demonstrated that indirect exposure humans to pharmaceuticals through the water could cause negative effects. Raw sewage and wastewater effluents are major sources found in surface waters drinking water. Therefore, it is important consider characterize efficiency pharmaceutical removal during drinking-water treatment ...

It is known that TiO2 exhibits good photocatalytic properties which could be used in various commercial applications such as water and air purification or photo-induced biodegradation of microbes. TiO2 occurs in nature in the form of three crystal polymorphs: anatase, brookite and rutile. For photocatalytic applications only anatase and rutile are of interest, however anatase shows greater phot...

A novel heterostructure was first synthesized by directly depositing photocatalytic inert ZnO2 onto facet {201} of brookite nanorods. The heterostructure thus obtained was found to show a superior photocatalytic activity under UV-light irradiation. The exceptional photocatalytic performance was due to the band-structure match between ZnO2 and brookite as well as synergic charge accumulation by ...

Oil sands process-affected water (OSPW) produced by the surface mining oil sands industry in Alberta, Canada, is toxic to aquatic organisms. Ozonation of OSPW attenuates this toxicity. Altered concentrations of sex steroid hormones, impaired reproductive performance, and less prominent secondary sexual characteristics have been reported for fish exposed to OSPW. However, the mechanism(s) by whi...

To investigate the effect of Gd doping on photocatalytic activity of BiFeO3 (BFO), Gd-doped BFO nanoparticles containing different Gd doping contents (Bi(1-x)GdxFeO3, x = 0.00, 0.01, 0.03, 0.05) were synthesized using a facile sol-gel route. The obtained products were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectra,...

This study investigated the reaction kinetics and degradation mechanism of parabens (methylparaben, ethylparaben, propylparaben and butylparaben) during ozonation. Experiments were performed at pH 2, 6 and 12 to determine the rate constants for the reaction of protonated, undissociated and dissociated paraben with ozone. The rate constants for the reaction of ozone with dissociated parabens (3....

Second-order rate constants of the direct ozone reactions [formula: see text] and the indirect OH radical reactions [formula: see text] for nine chemicals on the US EPA's Drinking Water Contaminant Candidate List (CCL) were studied during the ozonation and ozone/hydrogen peroxide advanced oxidation process (O(3)/H(2)O(2) AOP) using batch reactors. Except for the thiocarbamate herbicides (molina...