A novel prosthetic group, which is present in NADH dehydrogenase (EC 1.6.99.3) from Pepfosfrejfococcus etsdenii, has been purified and its physicochemical properties investigated. The chemical structure of this species has been established as the FAD analogue of 7-methyl-B-hydroxyisoalloxazine. The proposed structure is confirmed by: (a) chemical synthesis of 7-methyl-S-hydroxy-isoahoxazine mod...

Oxidizing agents attack the disulfide groups of the cystine in wool and increase the solubility of the wool in alkaline solutions. The determination of the alkalisolubility may be used as a measure of the extent to which the wool is oxidized. The method is applicaule as a control in practical processes, such as bleaching and chlorination, and offers a measure of the extent to which wool is degr...

Hadamard transform spatial multiplexing techniques are applied to laser densitometry in order to prevent the photo-induced degradation of sensitive materials. Photochemical and thermal degradations can often occur in point focused scanning laser densitometry. In spatial multiplexing, the excitation source is defocused and efficiently distributed throughout the sample, reducing local power densi...

The long-term goal of the project is to investigate the distributions of chromophoric dissolved organic matter (CDOM) in the New York/New Jersey Harbor and New York Bight system so as to facilitate a deeper understanding of the source and processes that control CDOM distributions in estuarine and coastal waters. CDOM source strengths and photochemical degradation processes were incorporated int...

The photochemical and photo-Fenton oxidation of 1,3-dichloro-2-propanol was performed in a batch reactor, at room temperature, using UV radiation, H2O2 as oxidant, and Fenton’s reagent. The effect of the oxidative agent’s initial concentration was investigated as well as the effect of the initial concentration of Fe(II) by following the target compound degradation, the total organic carbon remo...

Virgin olive oil is one of the essential products for the economy of Mediterranean countries. The possible residues of pesticides that can reach the oil may be a risk to public health, thus causing the prohibition of its marketing by the health authorities. This paper is a preliminary study on photochemical degradation of pesticide residues using a small-scale prototype (1L capacity). The metho...