in current work a comprehensive mechanism based on intermediate radical termination theory is assumed for raft polymerization of styrene over cumyl dithiobenzoate as raft agent. rate constants for addition (ka) and fragmentation reactions (kf) are set to 6×106 and 5×104 respectively, which lead to an equilibrium constant value of k = ka/kf = 1.2 x 102. moment equations method was used to model ...

in this work, based on experimental observations and exact theoretical predictions, the kinetic scheme of raft polymerization is extended to a wider range of reactions such as irreversible intermediate radical terminations and reversible transfer reactions. the reactions which have been labeled as kinetic scheme are the more probable existing reactions as the theoretical point of view. the deta...

This study presents a new approach for physical and material modeling of space frame-raft-soil system. The physical modeling consists of a modified Thimoshenko beam bending element with six degrees of freedom per node to model the beams and columns of the superstructure, a modified Mindlin's plate bending element with five degrees of freedom per node to represent the structural slabs and raft, ...