A mathematical model is developed to study the performance of a direct carbon solid oxide fuel cell system (DC-SOFC). Simulation results indicate that in anode supported configuration, design parameters (porosity, tortuosity and thickness) play very important role DC-SOFC, presented as polarization curve. The effect Ag content electrode found significant DC-SOFC. operating parameters, namely pr...

fuel cells belong to an avant-garde technology family for a wide variety of applications including micro-power, transportation power, stationary power for buildings and other distributed generation applications. the first objective of this contribution is to find a suitable reduced model of a solid oxide fuel cell (sofc). the derived reduced model is then used to design a state estimator. in th...

Yttria-stabilized zirconia (YSZ) is the best known ceramic-oxide material employed as a component of either solid electrolyte or anode cermet material for intermediate solid oxide fuel cell (IT SOFC). The properties of traditionally produced (by mechanical mixing of oxides) Al2O3/3YSZ composite with the same composition materials obtained by citrate and impregnation methods and with properties ...

A cobalt-based thermoelectric compound Ca(3)Co(2)O(6) (CCO) has been developed as new cathode material with superior performance for intermediate-temperature (IT) solid-oxide fuel cell (SOFC). Systematic evaluation has been carried out. Measurement of thermal expansion coefficient (TEC), thermal-stress (σ) and interfacial shearing stress (τ) with the electrolyte show that CCO matches well with ...

Solid oxide fuel cells (SOFC) are the cleanest, most efficient, and cost-effective option for direct conversion to electricity of a wide variety of fuels. While significant progress has been made in anode materials with enhanced tolerance to coking and contaminant poisoning, cathodic polarization still contributes considerably to energy loss, more so at lower operating temperatures. Here we rep...

This paper presents the work for efficiency enhancement on a hybrid power system with an irreversible Solid Oxide Fuel Cell (SOFC) and Stirling Engine (SE) various design using approach of finite-time thermodynamics. The SOFC-based cogeneration was integrated SE several heat components. effects configurations interface components performance were investigated. By analyzing thermodynamics consid...

Thermally robust and chemically inert Ag@SiO2 nanoprobes are employed to provide the surface enhanced Raman scattering (SERS) effect for an in situ/operando study of the early stage of carbon deposition on nickel-based solid oxide fuel cell (SOFC) anodes. The enhanced sensitivity to carbon enables the detection of different stages of coking, offering insights into intrinsic coking tolerance of ...

An 8 nm-thick gadolinium-doped ceria (GDC) layer was inserted as a cathodic interlayer between the nanoscale proton-conducting yttrium-doped barium zirconate (BZY) electrolyte and the porous platinum cathode of a micro-solid oxide fuel cell (μ-SOFC), which has effectively improved the cathode reaction kinetics and rendered high cell power density. The addition of the GDC interlayer significantl...