Membrane-based gas separation has attracted a great deal of attention recently due to the requirement for high purity gasses in industrial applications like fuel cells, and because of environment concerns, such as global warming. The current methods of cryogenic distillation and pressure swing adsorption are energy intensive and costly. Therefore, polymer membranes have emerged as a less energy...

Membrane gas separation at high temperatures and in the presence of aggressive chemicals, such as H2S, NH3, SOx, NOx hot water vapor, is attracting interest from both a fundamental industrial standpoint. To fully exploit benefits membrane technology, it imperative to develop materials that withstand thermally chemically harsh conditions, well understand principles underpinning transport species...

This research investigated stability of two novel aminated polyphenylene polymers as anion exchange layers in bipolar membranes. Bipolar membrane stability was tested under operating conditions of 50 mA/cm2, and under conditions of soaking in room temperature 1 M NaOH. The stability of the custom made bipolar membranes was compared with those for two commercial membranes. For the polyphenylene-...

Giant cell-like polymer vesicles, polymersomes, made from the diblock copolymer poly(ethylene oxide)-polybutadiene (PEO-PBD), have bilayer structures similar to the cell membrane but have superior and tunable properties for storage and stability. We have modified the terminal hydroxyl of the hydrophilic block with biotin-lysine (biocytin), a biologically derived group that imparts specific adhe...

Latex nanoparticles were packed inside nanometer-thick titania/polymer composite nanotubules templated by porous alumina membrane, to give free-standing particle-in-tubing "micro-beanpods" after removal of the template membrane.

A thin and compact mixed matrix membrane containing CAU-1-NH2 and the poly(methyl methacrylate) polymer has been originally synthesized. The as-prepared membrane exhibits high permeability of H2 and excellent H2/CO2 selectivity.

Native and synthetic membranes can be electrically monitored by creating supported lipid bilayers on top of conducting polymer electrodes. Cell membrane characteristics, e.g. the function transmembrane proteins, are studied in this paper, along with device sensitivity.

– We investigate the shape transformation of a vesicle incorporated with a long and flexible polymer. We evaluate the grand canonical partition function of the polymer to consider the effects of chain conformational changes on the membrane. It is found that the polymer loops with the ends adsorbed or anchored on the membrane play a major role on vesicular budding transition. The vesicle, one of...

This work demonstrates the synthesis, characterization and application of a hyperbranched polyethyleneimine/polysulfone (HPEI/PSf) thin fi lm composite (TFC) membrane. The membrane was accessed via an interfacial polymerization of trimesoyl chloride and HPEI. The membrane samples were characterized by Fourier Transform Infrared-Attenuated Total Refl ectance (FTIR-ATR) s...