Three austenitic alloys with different Ni content were stress corrosion cracking (SCC) tested in simulated pressurized water reactor (PWR) primary at 320 and 360 °C. Diffusion-induced grain boundary migration (DIGM) associated preferential intergranular oxidation (PIO) is observed ahead of all SCC crack tips. The occurrence DIGM revealed to be driven by PIO-induced diffusion Cr, Fe, Ni. extent ...