The synthesis of two-dimensional double metal cyanide complexes of the formula Co(H2O)2[M(CN)4].4H2O (M=Ni, Pd or Pt) and the X-ray crystal structure of Co(H2O)2[Pd(CN)4].4H2O are presented. The anhydrous forms of these complexes were found to be effective catalyst precursors for the homopolymerization of propylene oxide as well as the random copolymerization of propylene oxide and carbon dioxi...

highly active metallocenes and other single site catalysts have opened up the possibility of polymerizing cycloolefins such as norbornene (n) or of copolymerizing them with ethene (e) or propene (p). the polymers obtained show exciting structures and properties. e-n copolymers are industrially produced materials, with variable and high glass transitions depending on the wide range of their micr...

A set of new polymers that can be used as phase forming components in aqueous two-phase systems is presented. All polymers studied have thermoseparating properties i.e. form one separate polymer enriched phase and one aqueous solution when heated above the critical temperature. This property makes the polymers attractive alternatives to the polymers used in traditional aqueous two-phase systems...

Abstract The interface between polymer matrices and nanofillers is critical for efficient interaction to achieve the desired final properties. In this work, block copolymers were utilized control optimum interfacial interaction. Specifically, we studied compatibilizing effects of styrene-ethylene/butadiene-styrene (SEBS) styrene-ethylene/propylene (SEP) on morphology, conductivity, rheological ...

Propylene glycol is discharged to the surface and underground waters and vicinity soils via industrial wastewater effluents, posing many health and environmental risks. The main goal of this study was to remove propylene glycol from synthetic wastewater in a fixed bed activated sludge reactor. To observe the effects of organic loading on bioreactor performance, the organic loading was increased...

OBJECTIVES The primary objective was to evaluate the relationship between high-dose lorazepam and serum propylene glycol concentrations. Secondary objectives were a) to document the occurrence of propylene glycol accumulation associated with continuous high-dose lorazepam infusion; b) to assess the relationship between lorazepam dose, serum propylene glycol concentrations, and propylene glycol ...

Keratosis, one of the earliest skin manifestations of arsenicosis, can be treated by either oral or topical formulation of drug. In this study we examined the effectiveness and tolerance of propylene glycol for the treatment of arsenical palmer keratosis. Sixty patients of arsenicosis with palmer keratoses were randomly divided into three groups and different concentrations (15, 30 and 45%) of ...

The new highly active supported vanadium-magnesium catalyst (VMC) has been studied in α-olefin (1-butene, 1-hexene)/ ethylene copolymerization in the presence of hydrogen. Data on the effect of α-olefin/ethylene ratio in copolymerization on the content of branchings in copolymers, kinetic profile, copolymer yield, molecular weight and molecular weight distribution of copolymers have been obtain...

While crystallization behavior of isotactic polypropylene homopolymers had been subject to a wide range experimental and modeling studies, this is not the case for propylene-ethylene random copolymers (PPR). This class polymers offers up now significant challenges, both from an as well perspective. The ethylene incorporation in propylene chains, distribution comonomer, has marked effect on kine...

AIM This study aimed to evaluate penetration of propylene glycol into root dentine. METHODOLOGY Safranin O in propylene glycol and in distilled water were introduced into root canals with and without artificial smear layer. Dye diffusion through dentinal tubules was determined spectrophotometrically. The time required for dye to exit through the apical foramen using propylene glycol and disti...