The high-rate cyclability of Li-rich Mn-based oxide (LMO) is highly limited by the electrochemical polarization resulting from slow kinetic Li2MnO3 phase. Herein, Prussian blue (PB) coating layer with specific redox potential introduced as a functionalized interface to overcome side effect and escaping O on surface LMO, especially its poor rate capability. In detail, PB can restrict large LMO s...