A comparison has been drawn in pure anatase and rutile forms of TiO2 films with their respective nano crystalline forms as photoanodes in dye-sensitized solar cells. All the films have been synthesized by using sol-gel method. Crystalline nature of the films has been investigated by x-ray diffraction (XRD) and morphologies have been studied by scanning electron microscopy (SEM). The short-circu...

The physicochemical properties of titanium dioxide (TiO2) depend strongly on the crystal structure. Compared to anatase, rutile TiO2 has a smaller bandgap, higher dielectric constant, and refractive index, which are desired for thin films in many photonic applications. Unfortunately, fabrication usually requires temperatures that too high (>400 °C, often even 600–800 °C) applications involving,...

Zircon and rutile are common accessory minerals whose essential structural constituents, Zr, Ti, and Si can replace one another to a limited extent. Here we present the combined results of high pressure–temperature experiments and analyses of natural zircons and rutile crystals that reveal systematic changes with temperature in the uptake of Ti in zircon and Zr in rutile. Detailed calibrations ...

The SrTiO3 modified rutile TiO2 composite nanofibers were synthesized by a simple electrospinning technique. The result of XRD, SEM and TEM indicate that the SrTiO3/TiO2 heterojuction has been prepared successfully. Compared with the TiO2 and SrTiO3, the photocatalytic activity of the SrTiO3/TiO2 (rutile) for the degradation of methyl orange exhibits an obvious enhancement under UV illumination...

Abstract Pure and Cu doped anatase/rutile mixed TiO 2 nanomaterials were fabricated through sol-gel method. The obtained photocatalysts characterized by XRD, SEM, TEM, XPS, PL DRS, the influences of doping on structure photocatalytic property studied. results show that when molar ratios Cu/Ti are 1% 2%, promotes anatase → rutile phase transformation. When ratio is 4%, transformation inhibited. ...

Since crystal phase dominantly affects the properties of nanocrystals, phase control is important for the applications. To demonstrate the size dependence in anatase-rutile phase transition of titania, we used quantum-size titania prepared from the restricted number of titanium ions within dendrimer templates for size precision purposes and optical wave guide spectroscopy for the detection. Con...

The photocatalytic methanol reforming reaction has been studied using many different Pd/Pt loaded TiO2 powdered catalysts, focussing on the effect of weight loading and reaction phase on the rate of hydrogen production. The palladium/platinum weight loading dependence in the gas and liquid phase showed that independent of the phase of reaction, the amount of hydrogen produced from methanol refo...

High-quality single-crystalline SnO₂ nanorods were synthesized using a microwave-assisted solution method. The nanorods were characterized using X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), ultraviolet-visible and Raman spectroscopy, Brunauer-Emmett-Teller (BET), and electrical resistance measurements. The XRD pattern ind...

High performance is expected in dye-sensitized solar cells (DSSCs) that utilize one-dimensional (1-D) TiO2 nanostructures owing to the effective electron transport. However, due to the low dye adsorption, mainly because of their smooth surfaces, 1-D TiO2 DSSCs show relatively lower efficiencies than nanoparticle-based ones. Herein, we demonstrate a very simple approach using thick TiO2 electros...

Nitrogen-doped, porous rutile has been prepared by hydrothermal reaction of TiN in nitric acid, with the nitrogen atoms present in the interstitial sites and in the form of adsorbed nitrate ions. The N-rutile powder exhibits outstanding photocatalytic activity toward degradation of adsorbed methylene blue under visible light irradiation.