In this paper, the dehydration of xylose to furfural was carried out under atmospheric pressure and at the boiling temperature of a biphasic mixture of toluene and an aqueous solution of xylose, with sulfuric acid as catalyst plus an inorganic salt (NaCl or FeCl(3)) as promoter. The best yield of furfural was 83% under the following conditions: 150 mL of toluene and 10 mL of aqueous solution of...

Incubation of normal newborn pig aorta with [14C]valine yielded a labeled protein that was isolated and purified with salt-soluble elastin from copper-deficient pig aorta as carrier. The labeled protein is soluble in strong neutral salt solution in the cold. It coacervates reversibly and can be separated into a hydrophobic phase by centrifugation at 32-37”. The protein migrates on polyacrylamid...

The formation of the conductive TTF-TCNQ (tetrathiafulvalene– tetracyanoquinodimethane) charge-transfer salt via rupture of microencapsulated solutions of its individual components is reported. Solutions of TTF and TCNQ in various solvents are separately incorporated into poly(urea-formaldehyde) core–shell microcapsules. Rupture of a mixture of TTF-containing microcapsules and TCNQ-containing m...

A phase transition is observed between a one-phase disordered phase and an ordered phase with multilamellar (onion) structures in an off-critical mixture of D2O and 3-methylpyridine (3MP) containing 85 mM of a salt in the absence of a surfactant. The salt consists of hydrophilic cations and hydrophobic anions that interact asymmetrically with the solvent composition fluctuations inducing mesoph...

Chelating bis-N-heterocyclic carbene (bis-NHC) complexes of iron(ii) containing pyridyl ligands have been prepared by the reaction of [FeCl2L] [L = bipy (1), phen (2)] with [LiN(SiMe3)2] and a bis(imidazolium) salt. The [Fe(bis-NHC)L(I)2] complexes were active pre-catalysts in the oxidation of 1-phenylethanol with tert-butyl hydroperoxide in neat conditions, affording a quantitative yield of ac...

Transport properties are examined in some detail for samples of the low temperature molten salt N-propyl-N-methyl pyrrolidinium bis(fluorosulfonyl)imide [Pyr13][FSI] from two different commercial suppliers. A similar set of data is presented for two different concentrations of binary lithium-[Pyr13][FSI] salt mixtures from one supplier. A new and significantly different production process is us...

The consumption of sodium in excessive amount may lead to heart disease, which is the first leading cause of death in the United States. Process cheese is one of the high salt containing milk products. The objective of this study was to evaluate and compare the effects of potassium chloride (KCl) and potassium based emulsifying salts as a salt (NaCl) replacer on the chemical and microbiological...

This study summarizes the results of micropaleontological, sedimentological, and isotope geochemical analyses of cuttings from five deep wells drilled in the Great Salt Lake (Utah, USA). Spanning the last 5.0 million yrs, our environmental history of the Great Salt Lake distinguishes four intervals based on paleobiological and sedimentological characteristics, using a previously developed tephr...

The different genetic markers of pneumococcal transforming DNA are inactivated in solution at characteristic temperatures, analogous to melting points. These temperatures are spaced sufficiently to permit inactivation of the lower melting markers while the others are preserved intact.' Such partially inactivated DNA has been considered to be a mixture of native and denatured molecules.1 If this...

The kinetics of collagen reprecipitation from solutions of salt-extracted calf dermis in the presence of small amounts of mucopolysaccharide and nucleic acids (0.005 per cent in the final reaction mixture) has been reported by Wood (1960). The present paper is a parallel study using the same materials, and describes the electron microscopic (EM) morphology of the collagen precipitates replicate...