The generation and migration of slab-derived fluids modulate subduction zone seismicity, arc magmatism, deep volatile cycling. However, the redox species oxygen fugacity ( f O 2 ) (hereafter expressed as log units relative to fayalite–magnetite–quartz buffer, ?FMQ) are highly debated. Here we conducted phase equilibria modeling on altered oceanic crust (AOC) serpentinites along typical geotherm...